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Thiol–Ene (Click) Reactions as Efficient Tools for Terpene Modification
Asian Journal of Organic Chemistry ( IF 2.7 ) Pub Date : 2017-08-29 , DOI: 10.1002/ajoc.201700387
Maulidan Firdaus 1
Affiliation  

This Focus Review highlights the application of thiol–ene (click) chemistry to the production of a diverse range of materials that are derived from terpenes. To present an overview concerning the potency of terpenes as renewable resources, recent advances in their development by using synthetic organic chemistry are initially discussed. In addition, the use of thiol–ene chemistry as an efficient approach and versatile tool for noncatalytic carbon−heteroatom bond formation is briefly presented, including mechanistic and kinetic aspects, as well as some structural considerations, that is, the influence of the thiol and olefin structures, which should be well‐thought‐out before applying such chemistry. This discussion also covers how an initiator works and its effect on the reaction rate. Moreover, the utilization of thiol–ene reactions for the synthesis of terpene‐based valuable platform chemicals, monomers, and polymers, including recent examples that demonstrate its broad utility, are highlighted.

中文翻译:

硫醇-烯(点击)反应是萜烯修饰的有效工具

本《重点评论》重点介绍了硫醇-烯(点击)化学在生产各种源自萜烯的材料中的应用。为了提供有关萜烯作为可再生资源的潜力的概述,首先讨论了通过使用合成有机化学发展萜烯的最新进展。此外,简要介绍了使用硫醇-烯化学方法作为非催化的碳-杂原子键形成的一种有效方法和通用工具,包括机理和动力学方面,以及一些结构上的考虑,即硫醇和烯烃结构,应在应用此类化学物质之前进行深思熟虑。该讨论还涵盖了引发剂的工作方式及其对反应速率的影响。而且,
更新日期:2017-08-29
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