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Mechanical properties and grain orientation evolution of zirconium diboride-zirconium carbide ceramics
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2017-09-12 , DOI: 10.1016/j.jeurceramsoc.2017.09.013
A. D’Angio’ , J. Zou , J. Binner , Hai-Bin Ma , G.E. Hilmas , W.G. Fahrenholtz

The effect of ZrC on the mechanical response of ZrB2 ceramics has been evaluated from room temperature to 2000 °C. Zirconium diboride ceramics containing 10 vol% ZrC had higher strengths at all temperatures compared to previous reports for nominally pure ZrB2. The addition of ZrC also increased fracture toughness from 3.5MPam for nominally pure ZrB2 to 4.3MPam due to residual thermal stresses. The toughness was comparable with ZrB2 up to 1600 °C, but increased to 4.6MPam at 1800 °C and 2000 °C. The increased toughness above 1600 °C was attributed to plasticity in the ZrC at elevated temperatures. Electron back-scattered diffraction analysis showed strong orientation of the ZrC grains along the [001] direction in the tensile region of specimens tested at 2000 °C, a phenomenon that has not been observed previously for fast fracture (crosshead displacement rate = 4.0 mm min−1) in four point bending. It is believed that microstructural changes and plasticity at elevated temperature were the mechanisms behind the ultrafast reorientation of ZrC.



中文翻译:

二硼化锆-碳化锆陶瓷的力学性能和晶粒取向演变

从室温到2000°C,已经评估了ZrC对ZrB 2陶瓷机械响应的影响。与先前报道的标称纯ZrB 2相比,含10vol%ZrC的二硼化锆陶瓷在所有温度下均具有更高的强度。ZrC的添加还增加了断裂韧性3.5兆帕对于名义上纯的ZrB 24.3兆帕由于残留的热应力。在高达1600°C的温度下,韧性与ZrB 2相当,但增加到4.6兆帕在1800°C和2000°C下。高于1600°C的韧性增加是由于ZrC在高温下具有可塑性。电子背散射衍射分析表明,在2000°C下测试的试样的拉伸区域中,ZrC晶粒沿[001]方向具有强取向,这是以前从未观察到的快速断裂现象(十字头位移速率= 4.0 mm min)-1)四点弯曲。据信,高温下的微观结构变化和可塑性是ZrC超快速重新定向的机制。

更新日期:2017-09-12
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