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Low molecular weight gelators (LMWGs) for ionic liquids: the role of hydrogen bonding and sterics in the formation of stable low molecular weight ionic liquid gels
Green Chemistry ( IF 9.8 ) Pub Date : 2017-09-04 00:00:00 , DOI: 10.1039/c7gc02053h
Peter McNeice 1, 2, 3, 4 , Yingying Zhao 1, 2, 3, 4 , Jianxun Wang 1, 2, 3, 4 , Gerald F. Donnelly 1, 2, 3, 4 , Patricia C. Marr 1, 2, 3, 4
Affiliation  

Low molecular weight gelators capable of forming a gel with an ionic liquid are rare. We report the ability of 3 sugar based gelators from renewable resources (derived from isosorbide and mannitol) to form gels with 21 ionic liquids comprising a range of cations and anions that are commonly applied in a variety of technologies. It was found that the combined consideration of Kamlet–Taft values with ionic liquid size and shape gives a useful predictor of successful gel formation.

中文翻译:

用于离子液体的低分子量胶凝剂(LMWG):氢键和位阻在稳定的低分子量离子液体胶凝剂形成中的作用

能够与离子液体形成凝胶的低分子量胶凝剂很少。我们报告了来自可再生资源(源自异山梨醇和甘露醇)的3种基于糖的胶凝剂与21种离子液体形成凝胶的能力,这些离子液体包含一系列在各种技术中通常应用的阳离子和阴离子。研究发现,将Kamlet-Taft值与离子液体的大小和形状结合起来考虑,可以为成功形成凝胶提供有用的预测指标。
更新日期:2017-09-12
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