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A multiple switching diarylethene dimer with a bis(benzylene)amine-linked naphthalimide unit
Tetrahedron ( IF 2.1 ) Pub Date : 2017-09-11 , DOI: 10.1016/j.tet.2017.09.010
Shasha Wei , Xue Li , Congbin Fan , Gang Liu , Shouzhi Pu

A novel photochromic diarylethene dimer with a bis(benzylene)amine-linked naphthalimide unit was synthesized, and its photochemical properties were systematically studied. Upon irradiation with ultraviolet light, a singly-closed isomer and a fully-closed isomer were reversibly formed, which were confirmed by the results of Nuclear Magnetic Resonance spectroscopy (NMR) and High-Performance Liquid Chromatography (HPLC). Additionally, the diarylethene dimer could be used as a multi-addressable fluorescence switch when triggered by light, proton, and metal ions. Moreover, a logic circuit was constructed with the unimolecular platform by using the fluorescence intensity at 445 nm as output and appropriate combinational stimuli of UV light, Al3+, and EDTA as inputs.



中文翻译:

具有双(亚苄基)胺连接的萘二甲酰亚胺单元的多开关二芳基乙烯二聚体

合成了具有双(亚苄基)胺连接的萘二甲酰亚胺单元的新型光致变色二芳基乙烯二聚体,并对其光化学性质进行了系统的研究。在用紫外线照射时,可逆地形成单封闭的异构体和全封闭的异构体,这通过核磁共振光谱法(NMR)和高效液相色谱法(HPLC)的结果得以证实。另外,当被光,质子和金属离子触发时,二芳基乙烯二聚体可用作多址荧光开关。此外,通过使用在445 nm处的荧光强度作为输出并使用UV光,Al 3+和EDTA的适当组合刺激作为输入,使用单分子平台构建逻辑电路。

更新日期:2017-09-11
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