Synthetically and pharmaceutically useful vinyl sulfones and sulfonamides are synthesized by the direct coupling of thiosulfonates with alkenes and amines, respectively. Copper catalysts help to generate the sulfonyl group from thiosulfonates and to form the C(sp2)–S/N–S bonds of the organosulfur compounds. This paper discusses the scope of these reactions of aromatic and aliphatic thiosulfonates with alkenes and amines.

中文翻译：

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以硫代磺酸盐为磺酰化剂铜催化烯烃和胺磺酰化

合成和药学上有用的乙烯基砜和磺酰胺分别通过硫代磺酸盐与烯烃和胺的直接偶联合成。铜催化剂有助于从硫代磺酸盐生成磺酰基并形成有机硫化合物的 C(sp2)-S/N-S 键。本文讨论了芳香族和脂肪族硫代磺酸盐与烯烃和胺的反应范围。