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Effect of MgO on WO3/SiO2-catalyzed light olefin metathesis using different feedstocks
Molecular Catalysis ( IF 4.6 ) Pub Date : 2017-09-09 , DOI: 10.1016/j.mcat.2017.08.019
Weili Jiang , Xiuhao Mo , Shuo Feng , Feng Xu , Guanglin Zhou , Hongjun Zhou , Chunming Xu , Bo Chen

Different feedstocks were adopted to undergo reactions catalyzed by WO3/SiO2 and WO3/SiO2-MgO catalysts to better understand the effect of MgO on the process. The results of 1-butene self-metathesis show that, although the isomerization of 1-butene was clearly enhanced by MgO, the propylene selectivity was not improved because of insufficient 1-butene or ethylene. The main route to produce propylene in this system is through cross-metathesis of 1-butene and 2-butene. When propylene was used as the feed, more 2-butene, which was produced from propylene self-metathesis, was transformed into 1-butene by the addition of MgO, resulting in an improved metathesis performance between 1-butene and propylene. The cross-metathesis of 2-butene and ethylene, however, did not show an significant enhancement by MgO. In addition, the analysis on n-butene isomers distribution reveals that the presence of MgO is helpful in keeping the isomers at their theoretical values, leading to the good stability of the reactions. Lastly, a further comparison for the reactions between trans-2-butene and cis-2-butene demonstrates that there is little difference in their metathesis reactivity.



中文翻译:

MgO对不同原料WO 3 / SiO 2催化轻烯烃复分解的影响

采用不同的原料进行WO 3 / SiO 2和WO 3 / SiO 2催化的反应-MgO催化剂可更好地了解MgO对工艺的影响。1-丁烯自复分解的结果表明,尽管MgO明显增强了1-丁烯的异构化,但是由于1-丁烯或乙烯不足,丙烯的选择性没有得到改善。在该系统中生产丙烯的主要途径是通过1-丁烯和2-丁烯的交叉复分解。当使用丙烯作为进料时,更多的由丙烯自复分解反应生成的2-丁烯通过添加MgO转化为1-丁烯,从而提高了1-丁烯与丙烯之间的复分解性能。然而,2-丁烯和乙烯的交叉复分解并未显示出MgO的显着增强。另外,对n的分析-丁烯异构体的分布表明,MgO的存在有助于将异构体保持在其理论值,从而使反应具有良好的稳定性。最后,对反式-2-丁烯和顺式-2-丁烯之间反应的进一步比较表明,它们的复分解反应性几乎没有差异。

更新日期:2017-09-09
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