Dyes and Pigments ( IF 4.5 ) Pub Date : 2017-09-09 , DOI: 10.1016/j.dyepig.2017.09.009 Dongjun Xie , Tao Liu , Tack Ho Lee , Wei Gao , Cheng Zhong , Lijun Huo , Zhenghui Luo , Kailong Wu , Wentao Xiong , Jin Young Kim , Hyosung Choi , Yanming Sun , Chuluo Yang
A new small molecule acceptor of IDTCN with indaceno[2,1-b:6,5-b’]dithiophene as electron-donating core and CPTCN (2-(6-oxo-5,6-dihydro-4H-cyclopenta[c]thiophen-4-lidene)malononitrile) as electron-withdrawing end-capping group was synthesized and investigated in organic solar cells. The IDTCN shows strong and broad absorption with a high extinction coefficient and appropriate energy levels matching with wide bandgap donor polymer. The best device based on PBT1-EH:IDTCN exhibits an open circuit voltage (Voc) of 0.93 V, a short circuit current (Jsc) of 13.31 mA/cm2, a FF of 0.702, achieving a PCE of 8.69%.
中文翻译:
一种基于茚并[2,1-b:6,5-b']二噻吩和噻吩稠合端基的新型小分子受体,用于不含富勒烯的有机太阳能电池
一种新的IDTCN小分子受体,其具有茚并[2,1-b:6,5-b']二噻吩作为供电子核和CPTCN(2-(6-oxo-5,6-dihydro-4H-cyclopenta [ c合成并研究了作为吸电子封端基的[噻吩-4-亚甲基)丙二腈),并在有机太阳能电池中进行了研究。IDTCN表现出强而宽的吸收性,具有高消光系数和与宽带隙供体聚合物相匹配的适当能级。基于PBT1-EH:IDTCN的最佳器件具有0.93 V的开路电压(V oc),13.31 mA / cm 2的短路电流(J sc),0.702的FF,实现了8.69%的PCE。