The synthesis, crystal structure and magnetic studies are reported for a two-dimensional network of mixed-valent {Mn6} cages. The compound contains three different bridging ligands: pivalate, phenylphosphonate and partially deprotonated triethanolamine. The result of using three bridging ligands is a complex structure involving a {MnIII2MnII4} edge-sharing bitetrahedron that interlinks, forming a layered structure. Weak intercage interactions lead to a remarkably complicated magnetic behaviour, with a phase transition at 2.1 K leading to a canted antiferromagnetic state.

中文翻译：

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{Mn6} 笼的二维网络中自旋倾斜、超磁性、负矫顽力和慢弛豫的证据

报告了混合价 {Mn6} 笼的二维网络的合成、晶体结构和磁性研究。该化合物包含三种不同的桥连配体：新戊酸酯、苯基膦酸酯和部分去质子化的三乙醇胺。使用三个桥连配体的结果是一个复杂的结构，包括一个 {MnIII2MnII4} 边缘共享双四面体，该双四面体相互连接，形成层状结构。弱的笼间相互作用导致非常复杂的磁行为，2.1 K 处的相变导致倾斜的反铁磁状态。