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Micro-structure of ITO ceramics sintered at different temperatures and its effect on the properties of deposited ITO films
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2017-09-07 , DOI: 10.1016/j.jeurceramsoc.2017.09.008
Fangsheng Mei , Tiechui Yuan , Ruidi Li , Kai Qin , Libo Zhou , Wenjun Wang

Structural characterizations of two ITO ceramics that were respectively sintered at 1560 °C and 1600 °C were focused on and the results indicate that the lower sintering temperature is good for ITO ceramics to have the triangle fine grains, larger elemental concentration gradients of indium and tin and more content of In4Sn3O12 phase which displays the stronger grain orientation growth along the crystallographic direction of [0-11]. ITO films with 100 nm thickness deposited at 25 °C–230 °C were used to investigate the effect of micro-structure on the film properties. Grain orientation growth of In4Sn3O12 phase is conductive to form ITO films of columnar structure. Otherwise, uniform micro-structure and higher solubility of SnO2 in In2O3 main phase contribute to deposit ITO films of higher sheet resistance, less thickness uniformity and higher transmittance at 25 °C, smaller etching angle and lower etching rate at 230 °C.



中文翻译:

不同温度下烧结的ITO陶瓷的微观结构及其对沉积ITO膜性能的影响

重点研究了两种分别在1560°C和1600°C烧结的ITO陶瓷的结构表征,结果表明较低的烧结温度有利于ITO陶瓷具有三角形的细晶粒,较大的铟和锡元素浓度梯度In 4 Sn 3 O 12相的含量更高,沿[0-11]晶体学方向显示出更强的晶粒取向生长。在25°C–230°C下沉积的厚度为100 nm的ITO膜用于研究微观结构对膜性能的影响。In 4 Sn 3 O 12的晶粒取向生长相导电形成柱状结构的ITO膜。否则,均匀的微观结构和较高的SnO 2在In 2 O 3主相中的溶解度有助于沉积ITO膜,该ITO膜具有较高的薄层电阻,较小的厚度均匀性和25°C的较高透射率,较小的蚀刻角和较低的230°C的蚀刻速率C。

更新日期:2017-09-07
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