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β-Diketiminato–Germylene Complexes of Carbonyl Ruthenium: Synthesis, Structure, and Reactivity
European Journal of Inorganic Chemistry ( IF 2.3 ) Pub Date : 2017-09-07 11:02:22 , DOI: 10.1002/ejic.201700607
Peng Nie 1 , Yan Li 1 , Qian Yu 1 , Bin Li 1 , Hongping Zhu 1 , Ting-Bin Wen 1
Affiliation  

The reaction of the β-diketiminatochlorogermylene L(Cl)Ge {L = HC[C(Me)N-2,6-iPr2C6H3]2} with Ru3(CO)12 affords the Ge2Ru complex [L(Cl)Ge]2Ru(CO)3, which represents the first example of a halogermylene ruthenium complex and exhibits duel reactivity through the transformation of either the Cl or L ligands at the Ge atom or oxidative reactions at the Ru center.

中文翻译:

羰基钌的β-二酮亚氨基-亚芳基配合物:合成,结构和反应性

β-二叉基亚氨基氯锗L(Cl)Ge {L = HC [C(Me)N-2,6- i Pr 2 C 6 H 3 ] 2 }与Ru 3(CO)12的反应得到Ge 2 Ru络合物[L(Cl)Ge] 2 Ru(CO)3,代表卤化亚甲基钌络合物的第一个实例,并通过Ge原子上的Cl或L配体的转化或Ru中心的氧化反应表现出对映反应性。
更新日期:2017-09-07
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