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Tris(pentafluorophenyl)borane-Catalyzed Reactions of Siloxanes: A Combined Experimental and Computational Study
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2017-09-05 02:02:15 , DOI: 10.1002/ejoc.201700760 Jomon Mathew 1 , Katsuya Eguchi 2 , Yumiko Nakajima 2 , Kazuhiko Sato 2 , Shigeru Shimada 2 , Yoong-Kee Choe 3
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2017-09-05 02:02:15 , DOI: 10.1002/ejoc.201700760 Jomon Mathew 1 , Katsuya Eguchi 2 , Yumiko Nakajima 2 , Kazuhiko Sato 2 , Shigeru Shimada 2 , Yoong-Kee Choe 3
Affiliation
The results of a combined experimental and computational study on the reaction between a hydrosiloxane (1,1,3,3-tetramethyldisiloxane, silox-H) and a vinylsiloxane (1,1,3,3-tetramethyl-1,3-divinyldisiloxane, silox-vin) in the presence of B(C6F5)3 are reported. The theoretical results predict the preference of trisiloxane formation over hydrosilylation for this reaction.
中文翻译:
三(五氟苯基)硼烷催化的硅氧烷反应:组合的实验和计算研究
氢硅氧烷(1,1,3,3-四甲基二硅氧烷,silox-H)与乙烯基硅氧烷(1,1,3,3-四甲基-1,3-二乙烯基二硅氧烷,报道了在B(C 6 F 5)3存在下的silox-vin)。理论结果预测,对于该反应,三硅氧烷的形成优先于氢化硅烷化。
更新日期:2017-09-05
中文翻译:
三(五氟苯基)硼烷催化的硅氧烷反应:组合的实验和计算研究
氢硅氧烷(1,1,3,3-四甲基二硅氧烷,silox-H)与乙烯基硅氧烷(1,1,3,3-四甲基-1,3-二乙烯基二硅氧烷,报道了在B(C 6 F 5)3存在下的silox-vin)。理论结果预测,对于该反应,三硅氧烷的形成优先于氢化硅烷化。