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Atom-Economical Synthesis of Unsymmetrical Diaryl Selenides from Arylhydrazines and Diaryl Diselenides
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2017-09-05 02:00:49 , DOI: 10.1002/ejoc.201700938
Toshihide Taniguchi 1, 2 , Akinori Murata 2 , Motonori Takeda 1 , Takumi Mizuno 3 , Akihiro Nomoto 2 , Akiya Ogawa 2
Affiliation  

An atom-economical method for the synthesis of selenides from arylhydrazines and stoichiometric amounts of diselenides is explored; the protocol is performed under mild conditions, in air, and with a cheap base. Furthermore, it is environmentally friendly and low costing. This new and facile selenide synthesis affords unsymmetrical diaryl selenides in good yields.

中文翻译:

由芳基肼和二芳基二硒化物合成不对称二芳基硒化物的原子经济学

探索了一种从芳基肼合成硒化物和化学计量的二硒化物的原子经济方法。该协议是在温和的条件下,在空气中和廉价的基础上执行的。此外,它是环保的并且成本低廉。这种新的且容易的硒化物合成以良好的收率提供了不对称的二芳基硒化物。
更新日期:2017-09-05
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