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Crystallization of polypropylene in the presence of biomass-based fillers of different compositions
Polymer ( IF 4.6 ) Pub Date : 2017-09-04 , DOI: 10.1016/j.polymer.2017.09.006
Jordi Girones , Loan T.T. Vo , Jean-Marc Haudin , Lionel Freire , Patrick Navard

Natural fillers composed of cellulose, lignin and fillers with a varying lignin/cellulose ratio (flax, jute, curauà fibers and miscanthus stem fragments) were used to prepare composites with polypropylene using the same procedure, with or without a maleic anhydride–grafted polypropylene (MA-g-PP) coupling agent. A clear acceleration of the crystallization kinetics was observed in the presence of miscanthus stem fragments. For non-coupled composites, the size and aspect ratio of fragments had no significant influence onto the crystallization kinetics of polypropylene. The presence of the MA-g-PP coupling agent increased even more the kinetics. A clear effect of the nature of the polymers present in the filler was observed. There is a direct relationship between the values of the Avrami kinetic constant k for the six fillers and their lignin content, the more effective to enhance crystallization kinetics being pure cellulose. Lignin has no effect onto the crystallization kinetics of polypropylene.



中文翻译:

在不同组成的基于生物质的填料存在下聚丙烯的结晶

天然填料由纤维素,木质素和木质素/纤维素比变化的填料(亚麻,黄麻,咖喱粉纤维和猕猴桃茎碎片)组成,使用相同的步骤,用或不用马来酸酐接枝聚丙烯,用聚丙烯制备复合材料( MA- g -PP)偶联剂。在存在桔梗茎碎片的情况下,观察到结晶动力学的明显加速。对于非偶联复合材料,碎片的大小和长宽比对聚丙烯的结晶动力学没有显着影响。MA-g-PP偶联剂的存在甚至增加了动力学。观察到存在于填料中的聚合物的性质的明显效果。Avrami动力学常数之间存在直接关系对于六个填料及其木质素含量的k,更有效地增强结晶动力学的是纯纤维素。木质素对聚丙烯的结晶动力学没有影响。

更新日期:2017-09-04
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