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Fundamental chemistry of binary S,N and ternary S,N,O anions: analogues of sulfur oxides and N,O anions
Chemical Society Reviews ( IF 46.2 ) Pub Date : 2017-07-12 00:00:00 , DOI: 10.1039/c6cs00925e
Tristram Chivers 1, 2, 3, 4 , Risto S. Laitinen 5, 6, 7, 8, 9
Affiliation  

Binary S,N anions, e.g., NSN2− and SSNSS, and related ternary S,N,O anions such as the structural isomers NSO/SNO and SSNO are rarely mentioned in inorganic chemistry textbooks, despite the fact that their salts were synthesised and structurally characterised more than 30 years ago. These fundamentally important species and their conjugate acids, e.g. HNSO and HSNO, have been the focus of numerous investigations in recent years in view of their significance in disciplines as diverse as atmospheric chemistry and cell biology. This Tutorial Review provides a consolidated account of the fundamental chemistry including synthesis, spectroscopic characterisation, molecular and electronic structures, and properties of these intriguing species, and compares these aspects of their behaviour with those of isoelectronic sulfur oxides and N,O anions. A final section draws attention to the significance and applications of these simple S–N species in a broader context.

中文翻译:

二元S,N和三元S,N,O阴离子的基础化学:硫氧化物和N,O阴离子的类似物

二进制S,N阴离子,例如,NSN 2-和SSNSS - ,以及相关的三元S,N,O等阴离子作为结构异构体NSO - / SNO -和SSNO -无机化学教科书中很少被提及,尽管事实是它们的30多年来,合成了各种盐并对其结构进行了表征。鉴于它们在大气化学和细胞生物学等学科中的重要性,近年来,这些基本重要的物种及其共轭酸(例如HNSO和HSNO)已成为众多研究的重点。本教程复习提供了基本化学的综合说明,包括合成,光谱表征,分子和电子结构以及这些引人入胜的物种的性质,并将这些行为的这些方面与等电氧化硫和N,O阴离子进行了比较。最后一部分提请注意这些简单S–N物种在更广泛的背景下的重要性和应用。
更新日期:2017-08-29
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