Dyes and Pigments ( IF 4.5 ) Pub Date : 2017-08-26 , DOI: 10.1016/j.dyepig.2017.08.046 Nirma Maurya , Ashok Kumar Singh
A novel chromone based effectual molecular receptor S has been synthesized according to the excited state intramolecular proton transfer (ESIPT) and are shown the remarkable aggregation-induced emission enhancement (AIEE) in aqueous medium. S1 can be observed as fluorescent sensor for relay recognition of Cu2+ and CN− in aq. medium (10 mM HEPES buffer pH-7.4). Additionally the S1 was mimic as the function of a sequential logic circuit at molecular level based on “On–Off–On” sensing behavior by the inputs of Cu2+ and CN−. Further both S1 and S1-Cu2+ complex shows the antimicrobial activities against fungi: Bipolaris oryzae and Rhizoctonia solani using agar well diffusion method.
中文翻译:
通过Cu 2+感应关闭传感器进行CN −检测的间接方法:使用具有逻辑门和抗菌功能的新型AIEE荧光团
根据激发态分子内质子转移(ESIPT)合成了基于色酮的新型有效分子受体S,并显示了其在水性介质中的显着聚集诱导发射增强(AIEE)。S1可以观察到,作为铜的继电器识别荧光传感器2+和CN -的水溶液。培养基(10 mM HEPES缓冲液pH-7.4)。此外,该S1是模仿为顺序逻辑电路的在分子水平基于所述功能“开-关-开”,由Cu构成的输入感测行为2+和CN - 。此外,S1和S1-Cu 2+复合物均显示出对真菌的抗药性:米生双极杆菌和茄形丝枯菌 采用琼脂井扩散法。