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Ga and In modified ceria as supports for cobalt-catalyzed Fischer-Tropsch synthesis
Applied Catalysis A: General ( IF 5.5 ) Pub Date : 2017-08-24 , DOI: 10.1016/j.apcata.2017.08.026
Muthu Kumaran Gnanamani , Gary Jacobs , Wilson D. Shafer , Michela Martinelli , Donald C. Cronauer , A. Jeremy Kropf , Christopher L. Marshall , Burtron H. Davis

Ga- and In-modified ceria (Ce0.8Ga0.2O2, Ce0.8In0.2O2) materials were used as supports for cobalt-catalyzed Fischer-Tropsch synthesis (FTS). The addition of Ga to ceria was found to improve CO conversion for cobalt-catalyzed FTS, while the addition of In tended to decrease it. A similar trend was observed with the Ag-promoted cobalt/ceria catalysts. Doping of ceria with Ga or In decreased methane and increased the selectivity to olefins and alcohols for Ag-promoted cobalt/ceria. The sum of the products of olefins and alcohols for various catalysts exhibited a decreasing trend as follows: Ag-Co/Ce-Ga > Ag-Co/Ce-In > Ag-Co/Ce. Results of H2-TPR-XANES showed that adding of Ga or In to ceria increases the fraction of Ce3+ in the surface shell for both unpromoted and Ag-promoted catalysts in the range of temperature typical of catalyst activation. This partially reduced ceria plays an important role in controlling the product selectivity of cobalt-catalyzed FT synthesis.



中文翻译:

Ga和In修饰的二氧化铈作为钴催化费-托合成的载体

Ga-和In-改性的二氧化铈(Ce 0.8 Ga 0.2 O 2,Ce 0.8 In 0.2 O 2)材料用作钴催化费-托合成(FTS)的载体。发现在铈土中添加Ga可以改善钴催化FTS的CO转化率,而In的添加往往会降低CO转化率。用Ag促进的钴/二氧化铈催化剂观察到类似的趋势。用Ga或In掺杂二氧化铈减少了甲烷,并提高了Ag促进的钴/二氧化铈对烯烃和醇的选择性。用于各种催化剂的烯烃和醇的产物的总和表现出如下下降趋势:Ag-Co / Ce-Ga> Ag-Co / Ce-In> Ag-Co / Ce。H 2的结果-TPR-XANES表明,在催化剂活化的典型温度范围内,对于未促进的催化剂和Ag促进的催化剂,向二氧化铈中添加Ga或In会增加表面壳层中Ce 3+的比例。这种部分还原的二氧化铈在控制钴催化的FT合成的产物选择性中起着重要作用。

更新日期:2017-08-24
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