Ionic liquids are not innocent in Pd catalysis. C–H arylation of thiazolium and imidazolium ionic liquids with aryl halides,Organic Chemistry Frontiers

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Ionic liquids are not innocent in Pd catalysis. C–H arylation of thiazolium and imidazolium ionic liquids with aryl halides
Organic Chemistry Frontiers ( IF 5.4 ) Pub Date : 2017-06-19 00:00:00 , DOI: 10.1039/c7qo00331e
Takahide Fukuyama _{1,

2,

3,

4,

5} , Md. Taifur Rahman _{1,

2,

3,

4,

5} , Hiroshi Mashima _{1,

2,

3,

4,

5} , Hideo Takahashi _{1,

2,

3,

4,

5} , Ilhyong Ryu _{1,

2,

3,

4,

5}

Affiliation

The ionic liquids bearing an aromatic vinylic C–H moiety are not innocent during Pd-catalyzed cross-coupling reactions of aryl halides, since palladium-catalyzed direct C–H arylation of thiazolium and imidazolium ionic liquids competes.

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