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Environmentally friendly nitrogen-doped carbon quantum dots for next generation solar cells
Sustainable Energy & Fuels ( IF 5.6 ) Pub Date : 2017-08-09 00:00:00 , DOI: 10.1039/c7se00158d
Darragh Carolan 1, 2, 3, 4, 5 , Conor Rocks 1, 2, 3, 4 , Dilli Babu Padmanaban 1, 2, 3, 4 , Paul Maguire 1, 2, 3, 4 , Vladimir Svrcek 5, 6, 7, 8 , Davide Mariotti 1, 2, 3, 4
Affiliation  

Shine on you crazy carbon! In this work, nitrogen-doped carbon quantum dots (N-CQDs) are synthesized using a simple custom atmospheric pressure microplasma. The method is facile, rapid, and environmentally friendly and the N-CQDs can be produced in a few minutes with no need for high temperature, complicated chemical techniques, or surface ligands. The N-CQDs are formed using molecular precursors and can be produced in different solvent mixtures. Material characterization techniques show a high degree of nitrogen doping on the QD surface with the amount of nitrogen depending on initial reaction conditions. The N-CQDs show interesting quantum confined optical properties that depend on the amount of nitrogen incorporation. Importantly, the band energy structure of the N-CQDs is elucidated and they are incorporated into a photovoltaic device as the photoactive layer achieving an extraordinary open-circuit voltage of 1.8 V and a power conversion efficiency of 0.8% (champion device), amongst the highest reported to date for group IV and carbon based quantum dots.

中文翻译:

下一代太阳能电池的环保氮掺杂碳量子点

闪耀在您疯狂的碳上!在这项工作中,使用简单的定制大气压微等离子体合成了氮掺杂的碳量子点(N-CQD)。该方法简便,快速且对环境友好,无需高温,复杂的化学技术或表面配体,即可在几分钟内生产出N-CQD。N-CQD是使用分子前体形成的,可以在不同的溶剂混合物中生产。材料表征技术表明,在QD表面上氮的掺杂程度很高,这取决于初始反应条件。N-CQD显示出有趣的量子限制光学性质,该性质取决于氮的掺入量。重要的,
更新日期:2017-08-23
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