Abstract

Tf₂NH-catalyzed tandem 1,6-conjugate addition/Schmidt type rearrangement using vinyl azides and p-quinone methides to access a variety of β-bis-arylated amides is reported. The method is quick, efficient, mild, and high yielding with broad substrate scope.

Tf₂NH-catalyzed tandem 1,6-conjugate addition/Schmidt type rearrangement using vinyl azides and p-quinone methides to access a variety of β-bis-arylated amides is reported. The method is quick, efficient, mild, and high yielding with broad substrate scope.

中文翻译：

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Tf2NH催化的乙烯基叠氮化物与对醌醌的1,6-共轭加成反应：一种温和而高效的合成β-双-芳基酰胺的方法

摘要

报道了使用乙烯基叠氮化物和对苯醌甲基化物的Tf ₂ NH催化的串联1，6-共轭加成/ Schmidt型重排，以访问各种β-双芳基酰胺。该方法快速，高效，温和且产率高，具有广泛的底物范围。

报道了使用乙烯基叠氮化物和对苯醌甲基化物的Tf ₂ NH催化的串联1，6-共轭加成/ Schmidt型重排，以访问各种β-双芳基酰胺。该方法快速，高效，温和且产率高，具有广泛的底物范围。