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Manganese incorporated on glucose as an efficient catalyst for the synthesis of adipic acid using molecular O2 in aqueous medium
Applied Catalysis A: General ( IF 5.5 ) Pub Date : 2017-08-16 , DOI: 10.1016/j.apcata.2017.08.008
Sagar D. Nale , Pramod V. Rathod , Vrushali H. Jadhav

A new manganese incorporated on glucose catalyst [email protected]3H-NH2 was synthesized and well characterized using FT-IR, PXRD, EDAX, SEM, TEM, [13] C cross-polarization NMR and BET analysis. The catalyst thus synthesized was studied for its utility in the synthesis of industrially important chemical adipic acid starting from readily available cyclohexanone using molecular O2 as a source. Adipic acid was obtained in maximum yield of 82% using [email protected]3H-NH2 catalyst in water as a solvent. The catalyst was easily recovered and reused for minimum five runs without any significant loss in the yield of products. Using molecular O2 as an oxidant and water as a solvent, the reaction is very important from green chemistry perspectives and can also be industrially feasible.



中文翻译:

锰结合在葡萄糖上作为在水性介质中使用分子O 2合成己二酸的有效催化剂

合成了一种新的结合在葡萄糖催化剂上的新型锰[电子邮件保护的] 3 H-NH 2,并使用FT-IR,PXRD,EDAX,SEM,TEM,[13] C交叉极化NMR和BET分析对其进行了很好的表征。研究了这样合成的催化剂在工业上重要的化学己二酸的合成中的实用性,该合成己二酸是从现成的环己酮开始使用分子O 2作为来源。使用[电子邮件保护的] 3 H-NH 2催化剂在水中的溶剂作为溶剂,己二酸的最大产率为82%。催化剂很容易回收并重复使用最少5次,而产物的收率没有任何重大损失。使用分子O 2 作为氧化剂和水作为溶剂,从绿色化学的角度看,该反应非常重要,在工业上也是可行的。

更新日期:2017-08-16
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