Ferrocene‐based polymers have drawn much attention in the past decades due to their unique properties and promising applications. However, the synthesis of hyperbranched polymers is still a great challenge. Here, two ferrocene‐based hyperbranched polytriazoles with high molecular weights are facilely prepared by the click polymerization reactions of ferrocene‐containing diazides (1) and tris(4‐ethynylphenyl)amine (2) using Cu(PPh₃)₃Br as catalyst in dimethylformamide at 60 °C for 5 and 9 h in satisfactory yields of 54.0% and 52.3%. The resulting polytriazoles are soluble in common organic solvents and thermally stable, with 5% weight loss temperatures up to 307 °C. They can be used as precursors to produce nanostructured ceramics with good magnetizability by pyrolysis at elevated temperature.

中文翻译：

---

二茂铁基超支化聚三唑：点击聚合法合成及其作为前体在纳米结构磁陶瓷中的应用

在过去的几十年中，基于二茂铁的聚合物因其独特的性能和广阔的应用前景而备受关注。然而，超支化聚合物的合成仍然是巨大的挑战。在此，通过含二茂铁的叠氮化物（1）和三（4-乙炔基苯基）胺（2）的Cu（PPh ₃）₃的点击聚合反应，可以轻松制备两种高分子量的二茂铁基超支化聚三唑。Br在二甲基甲酰胺中的催化剂在60°C下反应5和9 h，收率令人满意，分别为54.0％和52.3％。所得的聚三唑可溶于常见的有机溶剂中，并且具有5％的失重温度（最高307°C）具有热稳定性。它们可以用作前体，通过高温热解生产具有良好磁化性的纳米结构陶瓷。