Abstract

Heteroatom-centered radicals show versatile reactivity and offer useful synthetic methods in organic chemistry. The development of new approaches for forming heteroatom-centered radicals has recently expanded the practicality of radical chemistry for synthesis. This review focuses on recent advances in reactions of representative heteroatom-centered radicals.

1 Introduction

2 Group 17 Elements: Chlorine and Bromine Radicals

3 Group 15 and Group 16 Elements

3.1 Nitrogen- and Oxygen-Centered Radicals

3.2 Phosphorus- and Sulfur-Centered Radicals

3.3 Other Radicals

4 Group 14 Elements: Silicon-Centered Radicals

5 Group 13 Elements: Boron-Centered Radicals

6 Conclusion

Heteroatom-centered radicals show versatile reactivity and offer useful synthetic methods in organic chemistry. The development of new approaches for forming heteroatom-centered radicals has recently expanded the practicality of radical chemistry for synthesis. This review focuses on recent advances in reactions of representative heteroatom-centered radicals.

1 Introduction

2 Group 17 Elements: Chlorine and Bromine Radicals

3 Group 15 and Group 16 Elements

3.1 Nitrogen- and Oxygen-Centered Radicals

3.2 Phosphorus- and Sulfur-Centered Radicals

3.3 Other Radicals

4 Group 14 Elements: Silicon-Centered Radicals

5 Group 13 Elements: Boron-Centered Radicals

6 Conclusion

中文翻译：

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杂原子中心自由基反应的最新进展

摘要

以杂原子为中心的自由基具有多种反应性，并在有机化学中提供了有用的合成方法。形成以杂原子为中心的自由基的新方法的发展最近扩大了自由基化学用于合成的实用性。这篇综述着眼于代表性的以杂原子为中心的自由基反应的最新进展。

1引言

2组17元素：氯和溴自由基

3组15和组16元素

3.1氮和氧中心自由基

3.2磷和硫为中心的自由基

3.3其他自由基

4组14元素：以硅为中心的基团

5组13元素：以硼为中心的自由基

六，结论

以杂原子为中心的自由基具有多种反应性，并在有机化学中提供了有用的合成方法。形成以杂原子为中心的自由基的新方法的发展最近扩大了自由基化学用于合成的实用性。这篇综述着眼于代表性的以杂原子为中心的自由基反应的最新进展。

1引言

2组17元素：氯和溴自由基

3组15和组16元素

3.1氮和氧中心自由基

3.2磷和硫为中心的自由基

3.3其他自由基

4组14元素：以硅为中心的基团

5组13元素：以硼为中心的自由基

六，结论