NHC-stabilized 1-hydrosilaimine: synthesis, structure and reactivity,Chemical Communications

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NHC-stabilized 1-hydrosilaimine: synthesis, structure and reactivity
Chemical Communications ( IF 4.9 ) Pub Date : 2017-07-06 00:00:00 , DOI: 10.1039/c7cc03912c
Debabrata Dhara _{1,

2,

3} , Thangavel Vijayakanth _{3,

4,

5,

6} , Milan Kr. Barman _{1,

2,

3} , Khevath Praveen Kumar Naik _{1,

2,

3} , Nicolas Chrysochos _{7,

8,

9,

10} , Cem B. Yildiz _{11,

12,

13,

14} , Ramamoorthy Boomishankar _{3,

4,

5,

6} , Carola Schulzke _{7,

8,

9,

10} , Vadapalli Chandrasekhar _{3,

4,

15,

16,

17} , Anukul Jana _{1,

2,

3}

Affiliation

Tata Institute of Fundamental Research Centre for Interdisciplinary Sciences 21
Narsingi
India
Department of Chemistry
Indian Institute of Science Education and Research (IISER)
Pune 411008
Institut für Biochemie
Ernst-Moritz-Arndt Universität Greifswald Felix-Hausdorff-Straße 4
D-17487 Greifswald
Germany
Department of Medicinal and Aromatic Plants
University of Aksaray
Aksaray
Turkey
National Institute of Science Education and Research
Bhimpur-Padanpur
Bhubaneswar-752050

A facile, straightforward synthesis of N-heterocyclic carbene (NHC)-stabilized 1-hydrosilaimine starting from a silicon(IV)-precursor is reported. It has been employed for the addition of an O–H bond of water under ambient conditions without any additional catalyst.

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