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Cross-coupling of aromatic esters and amides
Chemical Society Reviews ( IF 46.2 ) Pub Date : 2017-07-07 00:00:00 , DOI: 10.1039/c7cs00182g
Ryosuke Takise 1, 2, 3, 4 , Kei Muto 4, 5, 6, 7 , Junichiro Yamaguchi 4, 5, 6, 7
Affiliation  

Catalytic cross-coupling reactions of aromatic esters and amides have recently gained considerable attention from synthetic chemists as de novo and efficient synthetic methods to form C–C and C–heteroatom bonds. Esters and amides can be used as diversifiable groups in metal-catalyzed cross-coupling: in a decarbonylative manner, they can be utilized as leaving groups, whereas in a non-decarbonylative manner, they can form ketone derivatives. In this review, recent advances of this research topic are discussed.

中文翻译:

芳族酯和酰胺的交叉偶联

芳族酯和酰胺的催化交叉偶联反应在最近获得相当大的关注从合成化学家作为从头和有效的合成方法,以形成C-C和C -杂原子键。酯和酰胺可用作金属催化的交叉偶联中的可分散基团:以脱羰基方式,它们可用作离去基团,而以非脱羰基方式,它们可以形成酮衍生物。在这篇综述中,讨论了该研究主题的最新进展。
更新日期:2017-07-08
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