A revised pathway for the catalytic Staudinger amidation reaction is presented that involves the intervention of in situ-generated silyl esters as the species responsible for amidation.

中文翻译：

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硅在Staudinger催化酰胺化中的更关键作用：硅烷作为非无害还原剂

提出了一种改进的催化施陶丁格酰胺化反应的途径，该途径涉及原位产生的甲硅烷基酯作为负责酰胺化的物质的干预。