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Inside Cover: Solvent-Assisted Metal Metathesis: A Highly Efficient and Versatile Route towards Synthetically Demanding Chromium Metal–Organic Frameworks (Angew. Chem. Int. Ed. 23/2017)
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2017-04-27 18:36:51 , DOI: 10.1002/anie.201703997
Jun-Hao Wang 1 , Ying Zhang 2 , Mian Li 3 , Shu Yan 1 , Dan Li 4 , Xian-Ming Zhang 1
Affiliation  

Owing to their extraordinary robustness and high porosity, chromium(III)-based metal–organic frameworks (Cr-MOFs) have great potential, but they are currently difficult to synthesize. In their Communication on page 6478 ff., J. H. Wang, X. M. Zhang et al. describe the preparation of a variety of Cr-MOFs from the corresponding Fe-MOFs under mild conditions by solvent-assisted metal metathesis. This efficient and versatile strategy constitutes a promising route for the synthesis of stable MOFs.

中文翻译:

内页:溶剂辅助金属复分解:高效合成金属铬-有机骨架的高效途径(Angew。Chem。Int。Ed。23/2017)

铬(III)基金属有机骨架(Cr-MOFs)由于其非凡的坚固性和高孔隙率而具有巨大的潜力,但目前很难合成。在J.H. Wang,X.M.Zhang等人的《通讯》第6478页及其以后。美国专利No.5,775,837描述了通过溶剂辅助金属复分解在温和条件下由相应的Fe-MOF制备多种Cr-MOF的方法。这种有效且通用的策略构成了合成稳定MOF的有前途的途径。
更新日期:2017-05-24
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