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Partial Reduction and Selective Transfer of Hydrogen Chloride on Catalytic Gold Nanoparticles
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2017-04-28 02:55:50 , DOI: 10.1002/anie.201700282
Judit Oliver-Meseguer 1 , Antonio Doménech-Carbó 2 , Mercedes Boronat 1 , Antonio Leyva-Pérez 1 , Avelino Corma 1
Affiliation  

HCl in solution accepts electron density from Au NPs and partially reduces at room temperature, as occurs with other simple diatomic molecules, such as O2 and H2. The activation can be run catalytically in the presence of alkynes to give exclusively E-vinyl chlorides, after the regio- and stereoselective transfer of HCl. Based also on this method, vinyl chloride monomer (VCM) can be produced in a milder and greener way than current industrial processes.

中文翻译:

催化金纳米粒子上氯化氢的部分还原和选择性转移

溶液中的HCl接受Au NPs的电子密度,并在室温下部分还原,这与其他简单的双原子分子(例如O 2和H 2)一样。在HCl的区域和立体选择性转移之后,可以在炔烃的存在下催化进行活化,从而仅得到E-氯乙烯。同样基于此方法,可以以比当前工业过程更温和,更环保的方式生产氯乙烯单体(VCM)。
更新日期:2017-05-24
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