The controllable encapsulation of nanoentities (such as metal nanoparticles, quantum dots, polyoxometalates, organic and metallorganic molecules, biomacromolecules, and metal–organic polyhedra) into metal–organic frameworks (MOFs) to form composite materials has attracted significant research interest in a variety of fields. These composite materials not only exhibit the properties of both the nanoentities and the MOFs but also display unique and synergistic functionalities. Tuning the sizes, compositions, and shapes of nanoentities encapsulated in MOFs enables the final composites to exhibit superior performance to those of the separate constituents for various applications. In this tutorial review article, we summarized the state-of-the-art development of MOFs containing encapsulated tunable nanoentities, with special emphasis on the preparation and synergistic properties of these composites.

中文翻译：

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金属-有机框架内可调谐纳米结构的可控设计

将纳米实体（例如金属纳米粒子，量子点，多金属氧酸盐，有机和金属有机分子，生物大分子以及金属有机多面体）可控制地封装到金属有机框架（MOF）中以形成复合材料已引起了广泛的研究兴趣领域。这些复合材料不仅展现出纳米实体和MOF的特性，而且展现出独特而协同的功能。调整封装在MOF中的纳米实体的大小，组成和形状，可使最终的复合材料表现出优于各种应用中单独成分的性能。在本教程的评论文章中，我们总结了包含封装的可调纳米实体的MOF的最新发展，