This Review focuses on research oriented toward elucidation of the various aspects that determine adsorption of CO₂ in metal–organic frameworks and its separation from gas mixtures found in industrial processes. It includes theoretical, experimental, and combined approaches able to characterize the materials, investigate the adsorption/desorption/reaction properties of the adsorbates inside such environments, screen and design new materials, and analyze additional factors such as material regenerability, stability, effects of impurities, and cost among several factors that influence the effectiveness of the separations. CO₂ adsorption, separations, and membranes are reviewed followed by an analysis of the effects of stability, impurities, and process operation conditions on practical applications.

中文翻译：

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使用MOF捕获和分离CO ₂：计算和实验研究

这篇综述的重点是阐明确定金属有机骨架中CO _2的吸附以及从工业过程中发现的气体混合物中分离CO ₂的各个方面的研究。它包括能够表征材料，在此类环境中研究被吸附物的吸附/解吸/反应特性，筛选和设计新材料以及分析其他因素（例如材料可再生性，稳定性，杂质影响）的理论，实验和组合方法。 ，以及影响分离效果的几个因素中的成本。一氧化碳₂ 审查了吸附，分离和膜，然后分析了稳定性，杂质和工艺操作条件对实际应用的影响。