A family of 'windmill'-like {Cu6Ln12} complexes exhibiting single-molecule magnetism behavior and large magnetic entropy changes,Chemical Communications

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A family of 'windmill'-like {Cu6Ln12} complexes exhibiting single-molecule magnetism behavior and large magnetic entropy changes
Chemical Communications ( IF 4.9 ) Pub Date : 2017-03-24 00:00:00 , DOI: 10.1039/c7cc01382e
Dimitris I. Alexandropoulos _{1,

2,

3,

4} , Katye M. Poole _{1,

5,

6,

7} , Luis Cunha-Silva _{8,

9,

10,

11,

12} , Javeed Ahmad Sheikh _{1,

7,

13,

14} , Wolfgang Wernsdorfer _{15,

16,

17,

18,

19} , George Christou _{1,

5,

6,

7} , Theocharis C. Stamatatos _{1,

2,

3,

4}

Affiliation

Department of Chemistry
Brock University
L2S 3A1 St. Catharines
Canada
University of Florida
Gainesville
USA
REQUIMTE-LAQV & Department of Chemistry and Biochemistry
Faculty of Sciences
University of Porto
4169-007 Porto
Portugal
Texas A&M University
College Station
Institut Néel
CNRS & Université Grenoble Alpes
France
Physikalisches Institut
Karlsruhe Institute of Technology (KIT)

A family of nanosized {Cu6Ln12} clusters with a 'windmill'-like topology was prepared by the employment of 2,6-diacetylpyridine dioxime, in conjuction with bridging N3-, in 3d/4f-metal chemistry; the octadecanuclear compounds exhibit...

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