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Ni-Catalyzed regio- and stereoselective addition of arylboronic acids to terminal alkynes with a directing group tether
Chemical Communications ( IF 4.9 ) Pub Date : 2017-03-20 00:00:00 , DOI: 10.1039/c6cc10256e
Madala Hari Babu 1, 2, 3, 4 , Gadi Ranjith Kumar 1, 2, 3, 4, 5 , Ruchir Kant 2, 3, 4, 6 , Maddi Sridhar Reddy 1, 2, 3, 4, 5
Affiliation  

Addition of arylboronic acids to directing group tethered acetylenes in a regio and stereoselective manner using an inexpensive catalytic system is achieved for the first time to access highly sought after allyl/homoallyl alcohol/amine units.

中文翻译:

镍催化的芳基硼酸的区域选择性和立体选择性加成,并带有连接基团的末端炔烃

首次实现了使用廉价的催化体系以区域选择性和立体选择性的方式将芳基硼酸加成到系链的乙炔基上,从而获得了备受追捧的烯丙基/均烯丙基醇/胺单元。
更新日期:2017-03-21
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