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Heteroleptic C^N Cyclometalated Iridium Complexes Enabling Photochemical Isomerization To Remarkably Enhance Luminescent Performance Using 2-(Diphenylphosphino)phenol Auxiliary Ligand Organometallics (IF 2.8) Pub Date : 2024-03-18 Yuji Koga, Kaori Torii, Yuji Yamada, Satoshi Kawata, Kouki Matsubara
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Nickel Perfluoroalkyl Complexes Supported by Simple Acetate Coligands Organometallics (IF 2.8) Pub Date : 2024-03-14 Cherry Mae T. Ravidas, Scott T. Shreiber, Lukas Kletsch, Axel Klein, David A. Vicic
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Nitrene-Transfer Chemistry to C–H and C═C Bonds Mediated by Triangular Coinage Metal Platforms Supported by Triply Bridging Pnictogen Elements Sb(III) and Bi(III) Organometallics (IF 2.8) Pub Date : 2024-03-10 Meenakshi Sharma, Reece M. Fritz, Joseph O. Adebanjo, Zhou Lu, Thomas R. Cundari, Mohammad A. Omary, Amitava Choudhury, Pericles Stavropoulos
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Zwitterionic Cobalt(I)–NHC Complexes with Tetraphenylborate Ligation: Synthesis, Characterization, and Reactivity Organometallics (IF 2.8) Pub Date : 2024-03-07 Qingshan Wang, Xuebing Leng, Dongyang Wang, Sheng-Di Bai, Liang Deng
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(Primary Amido)-ene(amido) Ni(II) Catalysts Containing a P-Chirogenic Substituted Ferrocene Moiety for Highly Enantioselective Asymmetric Transfer Hydrogenation of Ketones Organometallics (IF 2.8) Pub Date : 2024-03-06 Hong Chen, Weiwei Zuo
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Fe(III) Bis-Alkynyls Supported by the TIM Macrocycle: Molecular and Electronic Structures and Altering the Nature of Charge Transfer Transitions through Reduction Organometallics (IF 2.8) Pub Date : 2024-03-06 Prakhar Gautam, Reese A. Clendening, Andrew T. Poore, Shiliang Tian, Tong Ren
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The Challenging Reaction of Cyclopropenones with Benzamide Catalyzed by Rh(III): A Computational Study Organometallics (IF 2.8) Pub Date : 2024-03-05 Luis F. Veiros, Paulo J. Costa, Frederico F. Martins, Chao Pi, Xiuling Cui, Maria José Calhorda
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Olefin Metathesis and Stereoselective Ring-Opening Metathesis Polymerization with Neutral and Cationic Molybdenum(VI) Imido and Tungsten(VI) Oxo Alkylidene Complexes Containing N-Chelating N-Heterocyclic Carbenes Organometallics (IF 2.8) Pub Date : 2024-03-04 Somnath Bhattacharya, Felix Ziegler, Dongren Wang, Wolfgang Frey, Michael R. Buchmeiser
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Nickel-Catalyzed Arylation/Lactonization Cascade Reactions for the Synthesis of Bicyclo[3.2.1]lactones Organometallics (IF 2.8) Pub Date : 2024-02-29 Austin Pounder, Eric Neufeld, Leanne D. Chen, William Tam
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Electrochemical Properties of a Pyridine-Tunable Trisferrocenylborane Organometallics (IF 2.8) Pub Date : 2024-02-27 Harvey Sharma, Mitchell J. Demchuk, Suman Debnath, Brady J. H. Austen, Marcus W. Drover
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Ni-Catalyzed Photochemial Sulfamidation of Aryl Chlorides with Soluble Organic Amine as Base Organometallics (IF 2.8) Pub Date : 2024-02-26 Geyang Song, Jiameng Song, Jianyang Dong, Gang Li, Juan Fan, Dong Xue
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Silver–N-Heterocyclic Carbenes in π–Activation: Synergistic Effects between the Ligand Ring Size and the Anion Organometallics (IF 2.8) Pub Date : 2024-02-27 Abigail Frith, Aimee K. Clarke, Alex Heyam, Jason M. Lynam, Paul D. Newman, William P. Unsworth, Charlotte E. Willans
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Synthesis of Guanamine-Based Ruthenium Pincer Complexes and Their Application in Catalytic (De)hydrogenation Reactions Organometallics (IF 2.8) Pub Date : 2024-02-24 Hendrik A. Kempf, Niklas F. Both, Carolin A. M. Stein, Anke Spannenberg, Kathrin Junge, Henrik Junge, Matthias Beller
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Bridging Bis(boryl) and Borylene Species Stabilized in the Coordination Sphere of Ruthenium Metals Organometallics (IF 2.8) Pub Date : 2024-02-24 Urminder Kaur, Shippy Jaiswal, Marie Cordier, Boniface P. T. Fokwa, Sundargopal Ghosh
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In Situ Brønsted Acid Activated Cyclometalated N-Heterocyclic Carbene-Au(III)-Sulfonamide Complexes as Precatalysts for Alkyne Activation in Benzofuran Synthesis Organometallics (IF 2.8) Pub Date : 2024-02-21 Otto Seppänen, Anna Lenarda, Martin Nieger, Juho Helaja
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Synthesis and Photochemistry of Tris(trimethoxysilyl)acyl-silanes and 1,4-Tetrakis(silyl)-1,4-bisacylsilanes Organometallics (IF 2.8) Pub Date : 2024-02-19 Thomas Lainer, Sabrina D. Pueschmann, Ana Torvisco, Roland C. Fischer, Michaela Flock, Michael Haas
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Ancillary Ligand-Free Mixed Chlorido/Isobutylaluminato Lanthanide Complexes in Isoprene Polymerization Organometallics (IF 2.8) Pub Date : 2024-02-19 Eric C. Moinet, Philipp Wetzel, Olivier Tardif, Cäcilia Maichle-Mössmer, Reiner Anwander
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Correction to “Mechanisms for the Oxidative Addition of Palladium(0) Complexes to Arenediazonium Salts” Organometallics (IF 2.8) Pub Date : 2024-02-18 Henrique Esteves, Vitor H. Menezes da Silva, Carlos R. D. Correia, Ataualpa A. C. Braga
The Acknowledgments section has been updated to reflect funding from the National Institutes of Health (NIH) (Award Number R35GM137971). H.E. (grant #2016/18061-4), V.H.M.d.S. (grant #2017/18207-1), C.R.DC. (grants #2014/25770-6 and #2013/07600-3), and A.A.C.B (grant #2015/01491-3) are grateful to the São Paulo Research Foundation (FAPESP) for financial support. V.H.M.d.S. also acknowledges support
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Construction of Diiron Diamond-Core Complexes Influenced by a Fluoroalkoxide Ligand Organometallics (IF 2.8) Pub Date : 2024-02-15 Miguel A. Chacon-Teran, Sidney E. Creutz, Rafael E. Rodriguez-Lugo, Serhiy Demeshko, Franc Meyer, Anna Kajetanowicz, Karol Grela
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Phosphinoyl-Substituted Ketenyl Anions: Synthesis and Substituent Effects on the Structural Properties Organometallics (IF 2.8) Pub Date : 2024-02-15 Mike Jörges, Sunita Mondal, Manoj Kumar, Prakash Duari, Felix Krischer, Julian Löffler, Viktoria H. Gessner
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Role of TMEDA in Iron-Catalyzed C(sp2)–C(sp3) Cross-Coupling Reactions: A Mechanistic Study Using DFT Calculations Organometallics (IF 2.8) Pub Date : 2024-02-15 Xin Wan, Tianchu Zhao, Qinghua Ren, Gangchang Zhou
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Reactivities of Some Unsaturated Hydrocarbons with the Half-Sandwich Complex [Re(η6-C6H6)(NCCH3)3]+ Organometallics (IF 2.8) Pub Date : 2024-02-15 Robin Bolliger, Emily Wolf, Olivier Blacque, Henrik Braband, Roger Alberto
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Pioneers and Influencers in Organometallic Chemistry: Professor David Carrillo Contreras, an Inspiring Contributor to Chemistry in Chile Organometallics (IF 2.8) Pub Date : 2024-02-15 Guillermo Ahumada, Néstor Novoa, Jocelyn Oyarce, Carolina Manzur, Jean-René Hamon
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Visible-Light Photohydrogenation of Ketones, Aldehydes, and Imines Using a Strongly Reducing Photosensitizer Organometallics (IF 2.8) Pub Date : 2024-02-13 Vinh Q. Dang, Thomas S. Teets
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Pioneers and Influencers in Organometallic Chemistry: Professor John E. Ellis Takes Metals to the Limit Organometallics (IF 2.8) Pub Date : 2024-02-12 Paul J. Fischer
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Trends in Structure and Ethylene Polymerization Reactivity of Transition-Metal Permethylindenyl-phenoxy (PHENI*) Complexes Organometallics (IF 2.8) Pub Date : 2024-02-14 Clement G. Collins Rice, Justin A. Hayden, Adam D. Hawkins, Louis J. Morris, Zoë R. Turner, Jean-Charles Buffet, Dermot O’Hare
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Synthesis of N-Heterocyclic Carbene Complexes by Oxidative Addition of 4-Iodo-imidazolium Salts Followed by an Unusual Rearrangement Organometallics (IF 2.8) Pub Date : 2024-02-14 Peter P. Parusel, Patrick D. Dutschke, Marian Hebenbrock, Alexander Hepp, Robert H. Morris, F. Ekkehardt Hahn
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Strong Be–Be Covalent Bond in Be2L2 and Na2Be2L2 Molecules with Cyano-Based Ligands Organometallics (IF 2.8) Pub Date : 2024-02-13 Forough Rezaie, Siamak Noorizadeh
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Reactivity of Nickel Complexes Bearing P(C═X)P Ligands (X = O, N) Toward Diazoalkanes: Evidence for Phosphorus Ylide Intermediates Organometallics (IF 2.8) Pub Date : 2024-02-12 María L. G. Sansores-Paredes, Max Wendel, Martin Lutz, Marc-Etienne Moret
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Theoretical Exploration of Rh/Cu Cooperative Catalysis in C–H Allylation of Benzamide with 1,3-Diene Organometallics (IF 2.8) Pub Date : 2024-02-06 Li-Feng Yao, Lei Zhang, De-Cai Fang
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Synthesis and Reactivity of Monometallic and Bimetallic 2-Phosphinoimidazole Complexes of Platinum Organometallics (IF 2.8) Pub Date : 2024-02-06 Aimee L. Schill, Erin E. Martinez, Alexandra J. S. Larson, Emma L. Richardson, Jacob A. Parkman, Kelton G. Forson, Sydney K. F. Pettit, Stacey J. Smith, David J. Michaelis
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Mechanistic Aspects of Rhodium-Catalyzed Isoprene Hydroformylation: A Computational Study Organometallics (IF 2.8) Pub Date : 2024-02-05 Katrin Köhnke, Ragnar Bjornsson, Walter Leitner, Andreas J. Vorholt
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Is Mn(I) More Promising Than Fe(II)─A Comparison of Mn vs Fe Complexes for Olefin Metathesis Organometallics (IF 2.8) Pub Date : 2024-02-05 Jan Pecak, Radu A. Talmazan, Dennis Svatunek, Karl Kirchner, Maren Podewitz
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Distinguishing the Internal/External Base-Assisted Deprotonation Mechanisms in Aromatic C–H Activation with the Pd(II)/LA Catalyst Organometallics (IF 2.8) Pub Date : 2024-02-05 Kaiwen Li, Hongwu Jiang, Shuangfeng Dong, Zhuqi Chen, Guochuan Yin
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A Cationic Pt(II) Dinitrogen Adduct: Synthesis and Characterization of a CCC-aNHC Pincer Pt Complex with Abnormal N-Heterocyclic Carbene Donor Arms Organometallics (IF 2.8) Pub Date : 2024-02-02 Evans Fosu, Nghia Le, Taofiq Abdulraheem, Bruno Donnadieu, Amanda L. Patrick, Charles Edwin Webster, T. Keith Hollis
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Mechanistic Investigation on Potassium Amide-Catalyzed Benzylic C–H Bond Addition of Alkylpyridines to Styrenes Organometallics (IF 2.8) Pub Date : 2024-02-02 Si-Yuan Li, Yuan Li, Hui-Zhen Du, Junliang Wu, Gen Luo, Bing-Tao Guan
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Comparison of the Catalytic Activity of Surface-Immobilized Copper Complexes with Phosphonate Anchoring Groups for Atom Transfer Radical Cyclizations and Additions Organometallics (IF 2.8) Pub Date : 2024-02-02 Sarah E. Maier, Thomas Nagel, Mustafa Turan, Elif Kaya, Wolfgang Frey, Michael Dyballa, Deven P. Estes
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Solid-State Phosphine Ligand Engineering via Postsynthetic Modification of Amine-Functionalized Metal–Organic Frameworks Organometallics (IF 2.8) Pub Date : 2024-01-31 Aidan F. Greene, Jiehye Shin, Casey R. Wade
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Observation and Characterization of Single Elementary Reactions of Organometallics Organometallics (IF 2.8) Pub Date : 2024-02-01 Konrad Koszinowski
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Synthesis and Reactivity of Functionalized Fluoro-Nickelacyclopentanes Organometallics (IF 2.8) Pub Date : 2024-02-01 Loïc P. Mangin, Luana L. T. N. Porto, Jeffrey S. Ovens, R. Tom Baker
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Bis(phenoxy-imine) Alkaline–Earth Complexes with Competing Binding Pockets Organometallics (IF 2.8) Pub Date : 2024-01-31 Rebecca L. Jones, Zoë R. Turner, Jean-Charles Buffet, Dermot O’Hare
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Introducing the Author’s Corner Organometallics (IF 2.8) Pub Date : 2024-01-30 Paul J. Chirik
Happy New Year! The arrival of 2024 brings an annual reflection about the strengths of Organometallics and what we can do to best grow the journal and expand on its value. One theme is pervasive─the success of the journal derives from our community of authors, reviewers, and readers. Virtual and special issues have been an effective means to increase engagement, as have Tutorials. This past year we
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Displacement of P-Stereogenic Phosphiranes from Rhodium by CO in Hydroformylation Catalysis Organometallics (IF 2.8) Pub Date : 2024-01-27 Ryan M. Tipker, Russell P. Hughes, David S. Glueck, Heather A. Spinney, Michael A. Brammer, Arnold L. Rheingold
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Infrared Spectroscopy as Process Analytics to Identify and Quantify Grignard Reagents Organometallics (IF 2.8) Pub Date : 2024-01-26 Eva Deitmann, Gabriele Menges-Flanagan, Dirk Ziegenbalg
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Zintl Ions and Phases Promote the Catalytic Hydrophosphination of Alkynes, Alkenes, and Imines Organometallics (IF 2.8) Pub Date : 2024-01-25 Benjamin L. L. Réant, Meera Mehta
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Synthesis and Characterization of Uranium Complexes Supported by Substituted Aryldimethylsilylanilide Ligands Organometallics (IF 2.8) Pub Date : 2024-01-25 Erik D. Reinhart, Chad M. Studvick, Aaron M. Tondreau, Ivan A. Popov, James M. Boncella
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Tertiary Arsine Ligands for Pd-Catalyzed Direct Arylation Organometallics (IF 2.8) Pub Date : 2024-01-24 Kenta Ogawa, Akifumi Sumida, Takashi Yumura, Hiroaki Imoto, Kensuke Naka
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Cesium Reduction of a Lithium Diamidochloroberyllate Organometallics (IF 2.8) Pub Date : 2024-01-24 Kyle G. Pearce, Michael S. Hill, Mary F. Mahon
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Rhodium Complexes with a Pyridine-2-yloxy-silyl-Based N,Si-Ligand: Bonding Situation and Activity as Alkene Hydrogenation Catalysts Organometallics (IF 2.8) Pub Date : 2024-01-23 Alejandra Gómez-España, Pilar García-Orduña, Fernando J. Lahoz, Israel Fernández, Francisco J. Fernández-Álvarez
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Diastereoselective and Reversible Metallacycle Formation by Attack of a Pt-PR2OH Group on a Coordinated Nitrile in Pt-Catalyzed Hydration Organometallics (IF 2.8) Pub Date : 2024-01-23 Jorge A. Garduño, Andrew J. Sasser, Hannah J. Sexton, Russell P. Hughes, David S. Glueck, Arnold L. Rheingold
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Ligand Reorganization in the Coordination Sphere of a CCC-NHC Pincer Fe Complex and Transient Absorption Spectroscopic Characterization of [(BuCiCiCBu)2Fe]I Organometallics (IF 2.8) Pub Date : 2024-01-19 Joshua Mensah, Venkata K. Adiraju, James D. Cope, Robert W. Lamb, Xiao X. Li, Bruno Donnadieu, Igor V. Rubtsov, Charles Edwin Webster, T. Keith Hollis
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Unveiling the Bonding Scenario in Metal–Aryne Complexes with EDA-NOCV Analyses Organometallics (IF 2.8) Pub Date : 2024-01-18 Sonam Suthar, Kartik Chandra Mondal
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Ligand Modifications on a Cp(quinolate)Ru Catalyst to Improve Its Stability in a Bio-orthogonal Deprotection Reaction Organometallics (IF 2.8) Pub Date : 2024-01-18 Jana Seefeldt, Reece G. Miller, Sascha Heinrich, Nils Metzler-Nolte
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Unraveling the Anticancer Efficacy and Biomolecular Properties of Ru(II)-Arene Complexes of Pyrene-Based Thiosemicarbazone Ligands: A Comprehensive In Silico/In Vitro Exploration Organometallics (IF 2.8) Pub Date : 2024-01-16 Vishnunarayanan Namboothiri Vadakkedathu Palakkeezhillam, Jebiti Haribabu, Vaishnu Suresh Kumar, Juan F. Santibanez, Vipin Manakkadan, Puthiyavalappil Rasin, Mohit Garg, Nattamai Bhuvanesh, Anandaram Sreekanth
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Chirality Transfer of Stereogenic Boron Centers Enabled by a SN2-Type Mechanism Organometallics (IF 2.8) Pub Date : 2024-01-16 Yannick Stöckl, Katrin Gugeler, Celine M. Holzwarth, Wolfgang Frey, Sascha Wegner, Birgit Claasen, Anna Zens, Dietrich Gudat, Christian P. Sindlinger, Johannes Kästner, Sabine Laschat
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Correction to “Comparisons of bpy and phen Ligand Backbones in Cr-Mediated (Co-) Electrocatalytic CO2 Reduction” Organometallics (IF 2.8) Pub Date : 2024-01-16 Amelia G. Reid, Megan E. Moberg, Connor A. Koellner, Juan J. Moreno, Shelby L. Hooe, Kira R. Baugh, Diane A. Dickie, Charles W. Machan
Page 1142 Table 1. The conditions for 2 + DBTD + PhOHc and 2 + Ph2DBTD + PhOHc should be changed to 2 + DBTD + PhOHg and 2 + Ph2DBTD + PhOHg. A new set of conditions should be added to the bottom of the table: g1.0 mM catalyst, 0.5 mM RM, 1.0 M PhOH. The contents of the following rows in Table 1 and the footnote should be changed as shown: –0.1 mM catalyst, 0.5 mM RM, and 0.12 M PhOH. –0.5 mM catalyst
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Metal–Ligand Cooperative Catalytic Coupling of Terminal Alkynes and Carboxylic Acids for the Stereoselective Synthesis of Dienyl Esters Organometallics (IF 2.8) Pub Date : 2024-01-12 Asaf Hassin, Romy Levy, Natalia Fridman, Mark Gandelman
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Four-Coordinate Co(III) Imide with an Unusually Tilted Terminal Imido Ligand Organometallics (IF 2.8) Pub Date : 2024-01-12 Li Gu, Addison Fraker, Niklas B. Thompson, Alex McSkimming
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σ3/σ5-P Tautomerism and Coordination Behavior of α,α-Dialkyl-2-(diphenylphosphino)benzenemethanols Organometallics (IF 2.8) Pub Date : 2024-01-12 Robert W. Baker, William Lewis, Ian J. Luck