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Synthesis of R-GABA Derivatives via Pd(II) Catalyzed Enantioselective C(sp3)-H Arylation and Virtual Validation with GABAB1 Receptor for Potential leads Chem. Asian J. (IF 4.1) Pub Date : 2024-03-18 Smitha Mohanlal, Diprupa Saha, Shubhant Pandey, Rudresh Acharya, Nagendra K Sharma
GABA (γ-amino butyric acid) analogues like baclofen, tolibut, phenibut, etc., are well-known GABAB1 inhibitors and pharmaceutically important drugs. However, there is a huge demand for more chiral GABA aryl analogues with promising pharmacological actions. Here, we demonstrate the chiral ligand acetyl-protected amino quinoline (APAQ) mediated enantioselective synthesis of GABAB1 inhibitor drug scaffolds
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Nucleophilic Selenocyclization Reaction of Benzodiynes Promoted by Sodium Selenide: Synthesis of Isoselenochromenes Chem. Asian J. (IF 4.1) Pub Date : 2024-03-18 Adriano Maroneze, Fabíola Caldeira, Davi Back, Cristina Nogueira, Gilson Zeni
We describe here the synthesis of isoselenochromenes via a nucleophilic selenocyclization reaction of benzodiynes with sodium selenide. The central parameters that affect this cyclization reaction were studied, and the best reaction conditions were applied to different substrates to determine the scope of the method. The results indicated that isoselenochromenes were obtained in higher yields when
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Revisiting Stereoselective Propene Polymerization Mechanisms: Insights through the Activation Strain Model Chem. Asian J. (IF 4.1) Pub Date : 2024-03-17 Eugenio Romano, Vincenzo Barone, Peter H.M. Budzelaar, Claudio De Rosa, Giovanni Talarico
The stereoelectronic factors responsible for stereoselectivity in propene polymerization with several metallocene and post-metallocene transition metal catalysts have been revisited using a combined approach of DFT calculations, the Activation Strain Model, Natural Energy Decomposition Analysis and a molecular descriptor (%VBur). There are in most cases two different paths leading to the formation
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Electro‐oxidative methylation of 2‐isocyanobiaryls using N,N‐dimethylformamide (DMF) as carbon source: Synthesis of 6‐methylphenanthridines Chem. Asian J. (IF 4.1) Pub Date : 2024-03-16 Kannika La-ongthong, Teera Chantarojsiri, Darunee Soorukram, Pawaret Leowanawat, Vichai Reutrakul, Chutima Kuhakarn
A benign electrochemical method to access 6‐methylphenanthridines from 2‐isocyanobiaryls using N,N‐dimethylformamide (DMF) as a methyl source is reported. The protocol operates at ambient temperature without the need for harmful methylating reagents. Mechanistic studies suggested that DMF delivered a methylene synthon, followed by reduction at the cathode and tautomerization. The method offers environmental
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Dual Functional Microcapsule based on Monodisperse Short PEG Amphiphile for Drug Encapsulation and Protein Affinity Controlled Release Chem. Asian J. (IF 4.1) Pub Date : 2024-03-15 Rohit N. Ketkar, Paritosh Dey, Triveni Sodnawar, Shilpy Sharma, Manikandan M, Sharmistha Dutta Choudhury, Nabanita Sadhukhan
A short monodisperse poly(ethylene glycol) (PEG) and a neutral organic rotamer conjugate TEG‐BTA‐2 amphiphile was designed for the construction of a stimuli‐responsive switchable self‐assembled structure for drug encapsulation by noncovalent interaction and targeted controlled delivery. A short PEG, tetraethylene glycol (TEG) was covalently attached with a neutral organic rotamer benzothiazole dye
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Synthesis of Naphthalimide Azocarboxylates Showing Turn‐on Fluorescence by Substitution Reaction With Sulfinates Chem. Asian J. (IF 4.1) Pub Date : 2024-03-14 Hiroki Tanimoto, Shogo Kyogaku, Aoi Otsuki, Takenori Tomohiro
The synthesis and characterization of sulfinate addition‐responsive fluorescent molecules are described. We found that addition reaction of sulfinates to naphthalimide‐substituted azocarboxylates afforded the corresponding sulfonyl hydrazides with high fluorescence quantum yields (up to 0.91 in THF and 0.54 in methanol), which exhibited a large Stokes shift (105 nm) in protic methanol solvent, while
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Facile Preparation of Impalement Resistant, Mechanically Robust and Weather Resistant Photothermal Superhydrophobic Coatings for Anti‐/De‐icing Chem. Asian J. (IF 4.1) Pub Date : 2024-03-14 Jinfei Wei, Weidong Liang, Mingyuan Mao, Bucheng Li, Junping Zhang
Photothermal superhydrophobic coatings hold great promise in addressing the limitations of conventional superhydrophobic anti‐icing coatings. However, developing such coatings with excellent impalement resistance, mechanical robustness and weather resistance remains a significant challenge. Here, we report facile preparation of robust photothermal superhydrophobic coatings with all the above advantages
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Front Cover: Interfacial Activity of Janus Particle: Unity of Molecular Surfactant and Homogeneous Particle (Chem. Asian J. 5/2024) Chem. Asian J. (IF 4.1) Pub Date : 2024-03-14 Haipeng Liu, Yingchun Long, Fuxin Liang
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Wet‐chemical Synthesis of Elemental 2D Materials Chem. Asian J. (IF 4.1) Pub Date : 2024-03-12 XU Yue, QI Junlei, MA Cong, Qiyuan HE
Wet‐chemical synthesis refers to the bottom‐up chemical synthesis in solution, which is among the most popular synthetic approaches towards functional two‐dimensional (2D) materials. It offers several advantages including cost‐effectiveness, high yields, and precious control over the production process. As an emerging family of 2D materials, elemental 2D materials (Xenes) have shown great potential
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Carbazole Based Smaragdyrins: Synthesis, Aromaticity Switching, and Formation of a Spiro‐Dimer Chem. Asian J. (IF 4.1) Pub Date : 2024-03-09 Jinchao Chen, Haigen Nie, Yutao Rao, Ling Xu, Mingbo Zhou, Bangshao Yin, Jianxin Song, Atsuhiro Osuka
Carbazole‐incorporated smaragdyrin BF2‐complex 3 was synthesized by SNAr reaction of 3,5‐dibromo‐8‐mesityl‐BODIPY 1 with 3,6‐di(tert‐butyl)‐1,8‐di(pyrrol‐2‐yl)carbazole 2 as a nucleophile. Demetalation of 3 with ZrCl4 gave the corresponding smaragdyrin free base 4 in a good yield. Oxidations of 3 and 4 with MnO2 gave smaragdyrins 5 and 6, respectively, both followed by aromaticity switching, since
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0‐D and 1‐D Perovskite‐like Hybrid Bismuth(III) Iodides Chem. Asian J. (IF 4.1) Pub Date : 2024-03-08 Aditi Saraswat, Pratap Vishnoi
Low‐dimensional hybrid bismuth halide perovskites have recently emerged as a class of non‐toxic alternative to lead perovskites with promising optoelectronic properties. Here, we report three hybrid bismuth(III)‐iodides: 0‐D (H2DAC)2Bi2I10·6H2O (H2DAC_Bi_I), 0‐D (H2DAF)4Bi2I10·2I3·2I·6H2O (H2DAF_Bi_I), and 1‐D (H2DAP)BiI5 (H2DAP_Bi_I) (where H2DAC = trans‐1,4‐diammoniumcyclohexane; H2DAF = 2,7‐diammoniumfluorene
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Frustrated Lewis Pair‐Type Reactivity of Intermolecular Rare‐Earth Aryloxide and N‐Heterocyclic Carbene/Olefin Combinations Chem. Asian J. (IF 4.1) Pub Date : 2024-03-07 Yiwen Guan, Kejian Chang, Yujie Su, Xian Xu, Xin Xu
This work reports the cooperative reactivity of rare‐earth aryloxide complexes with N‐heterocyclic carbene (NHC) or N‐heterocyclic olefin (NHO), showcasing their synergistic effect in the activation of H2 and diverse organic substrates. Reactions of RE(OAr)3 (RE = La, Sm, and Y; Ar = 2,6‐tBu2‐C6H3) with unsaturated NHC ItBu (:C[N(R)CH]2, R = tBu) isolate abnormally bound RE metal NHC complexes RE/aNHC
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Recent Advances of Chiral Small Organic Molecules: Structure and Properties for Circularly Polarized Luminescence Chem. Asian J. (IF 4.1) Pub Date : 2024-03-07 Tingwei Zhang, Yue Zhang, Zhiyuan He, Tingjun Yang, Xu Hu, Tengfei Zhu, Yuhai Tang, Yanfeng Zhang, Jiao Jiao
Circularly polarized luminescence (CPL) refers to the emission of light with distinguishable left or right circular polarization in non‐racemic systems. CPL has attracted significant attention due to its potential applications in future displays, photonics technologiesIn recent years, there has been significant development in the field of circularly polarized luminescent (CPL) materials based on small
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Recent Advances in NHC‐Catalyzed Chemoselective Activation of Carbonyl Compounds Chem. Asian J. (IF 4.1) Pub Date : 2024-03-07 Yixian Huang, Xiaolin Peng, Tingting Li
N‐Heterocyclic carbenes (NHCs) catalysts have been employed as effective tools in the development of various reactions, which have made notable contributions in developing diverse reaction modes and generating significant functionalized molecules. This review provides an overview of the recent advancements in the chemo‐ and regioselective activation of different aldehydes using NHCs, categorized into
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Hard Carbon Derived From Different Precursors for Sodium Storage Chem. Asian J. (IF 4.1) Pub Date : 2024-03-06 Wanli Wang, Bin Wang, Yuqi Li, Ning Wang, Yujie Xu, Chongze Wang, Yi Sun, Han Hu
Due to the almost unlimited resource and acceptable performance, Sodium‐ion batteries (SIBs) have been regarded as a promising alternatives for lithium‐ion batteries for grid‐scale energy storage. As the key material of SIBs, hard carbon (HC) plays a decisive role in determining the batteries’ performance. Nevertheless, the micro‐structure of HCs is quite complex and the random organization of turbostratically
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Recent Advances in Detection of Hydroxyl Radical by Responsive Fluorescence Nanoprobes Chem. Asian J. (IF 4.1) Pub Date : 2024-03-06 Mazen Alanazi, Jiaxi Yong, Miaomiao Wu, Zexi Zhang, Dihua Tian, Run Zhang
Hydroxyl radical (•OH), a highly reactive oxygen species (ROS), is assumed as one of the most aggressive free radicals. This radical has a detrimental impact on cells as it can react with different biological substrates leading to pathophysiological disorders, including inflammation, mitochondrion dysfunction, and cancer. Quantification of this free radical in‐situ plays critical roles in early diagnosis
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Two energetic framework materials based on DNM‐TNBI as host molecule: Effectively coordinated by different cations Chem. Asian J. (IF 4.1) Pub Date : 2024-03-06 Boqian Yang, Bibo Li, Yang Liu, Chuanhao Xu, Shangbiao Feng, Shuhai Zhang
With the demand to develop outstanding‐performance energetic materials, 1‐(dinitromethyl)‐4,4',5,5'‐tetranitro‐1H,1'H‐2,2'‐biimidazole (DNM‐TNBI) emerged as a great contender (D: 9102 m·s‐1; P: 37.6 GPa). However, the relatively poor thermal stability (Td: 142 ℃) limits its practical application. In this study, DNM‐TNBI as a host molecule to synthesize two new energetic open‐framework materials by
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Controllable Chemoselectivity Cascade Reactions for the Synthesis of Phenanthrenols via Palladium‐Catalyzed‐Suzuki/Heck Reaction and Michael Addition Chem. Asian J. (IF 4.1) Pub Date : 2024-03-05 Phornphan Yongpanich, Kamonlak Chatrangsan, Jumreang Tummatorn, Charnsak Thongsornkleeb, Somsak Ruchirawat
Palladium serves as a multi‐functional catalyst which is controllable by tuning reaction conditions. This work demonstrated the utilization of a palladium catalyst for the synthesis of phenanthrenols by cascade palladium‐catalyzed Suzuki/Heck reaction between chalcone and 2‐bromophenylboronic acid, followed by Michael addition. The sequential reaction could be controlled by reactivity of the palladium
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Copper Oxide Anchored Carbon Nanofibers: A Versatile Platform for Multiplex Detection of Antibiotics, Heavy Metals and Pesticides Chem. Asian J. (IF 4.1) Pub Date : 2024-03-05 Smriti Mishra, Yashmeen Budania, Ankit Tyagi, Sheelendra Singh, Pradip Kumar, Shiv Singh
Electrochemical sensors offer promising prospects for real‐time pollutant monitoring. In this study, copper oxide‐dispersed graphitic carbon nanofibers (CuO‐CNFs) grown via chemical vapour deposition were employed as a robust platform for detecting a variety of environmental pollutants. This array‐based sensor adeptly identifies three different classes of analytes, i.e., antibiotics (chloramphenicol
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Synthesis of Diaryl Tellurides with Sodium Aryltellurites under Mild Conditions Chem. Asian J. (IF 4.1) Pub Date : 2024-03-05 Shan Li, Yuan Cao, Lvqi Jiang, Jie Liu
A highly efficient new protocol has been developed for the formation of C‐Te bonds, leading to both symmetrical and unsymmetrical diaryl tellurides. This protocol utilizes sodium aryltellurites (4), which can be easily prepared from low‐cost aryltelluride trichlorides and NaOH. The synthesis involves the use of 4 and arylazo sulfones as starting materials in the presence of (MeO)2P(O)H. A variety of
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Recent Advances of Aminopeptidases‐Responsive Small‐Molecular Probes for Bioimaging Chem. Asian J. (IF 4.1) Pub Date : 2024-03-04 Chengyan Xu, Kaixi Cui, Zhifei Ye, Yurong Feng, Huabin Wang, Hongwen Liu
Aminopeptidases, enzymes with critical roles in human body, are emerging as vital biomarkers for metabolic processes and diseases. Aberrant aminopeptidase levels are often associated with diseases, particularly cancer. Small‐molecule probes, such as fluorescent, fluorescent/photoacoustics, bioluminescent, and chemiluminescent probes, are essential tools in the study of aminopeptidases‐related diseases
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Tuning Sensing Efficacy: The Influence of Alkyl Substituents on Metal Ion Detection at Mesoscopic Interface Chem. Asian J. (IF 4.1) Pub Date : 2024-03-04 Harshal V. Barkale, Nilanjan Dey
In this work, we conducted a comparative analysis of the metal ion sensing capabilities of two pyridine‐end oligo p‐phenylenevinylene compounds featuring different alkyl substituents (‐C4H9 and ‐C16H33) within a micelle medium. Our findings revealed a correlation between the positioning of the probe molecules within the micelle and the length of the alkyl chains, impacting their self‐assembly tendencies
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Water‐Doped Brønsted Acidic Protic Ionic Liquids for Enhanced Tributyl Citrate Synthesis in a Two‐Phase Esterification System Chem. Asian J. (IF 4.1) Pub Date : 2024-03-04 Justyna Więcławik, Alina Brzeczek-Szafran, Natalia Barteczko, Anna Chrobok
Tributyl citrate (TBC) plays a crucial role as a plasticizer, enhancing the flexibility of polymers like polyvinyl chloride. Its biodegradability and non‐toxic nature contribute to its eco‐friendly appeal, making it a preferred additive in diverse industries, including food packaging, medical devices, toys, and consumer goods. Herein, a method for the synthesis of TBC using inexpensive Brønsted acidic
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Unraveling Ferroptosis Mechanisms: Tracking Cellular Viscosity with Small Molecular Fluorescent Probes Chem. Asian J. (IF 4.1) Pub Date : 2024-03-02 Niharika Pareek, Sana Mendiratta, Nripankar Kalita, Shreya Sivaramakrishnan, Rafique Sanukhan, Animesh Samanta
Ferroptosis is a recently identified form of regulated cell death characterized by iron accumulation and lipid peroxidation. Numerous functions for ferroptosis have been identified in physiological as well as pathological processes, most notably in the treatment of cancer. The intricate balance of redox homeostasis is profoundly altered during ferroptosis, leading to alteration in cellular microenvironment
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Hollow nitrogen‐doped carbon spheres as zincophilic sites for Zn flow battery Chem. Asian J. (IF 4.1) Pub Date : 2024-03-02 Han Shi, Hui Pan, Peng Kang
Severe dendrite growth on Zn anodes poses a significant challenge to the development of Zn‐based batteries. An effective strategy for inhibiting the formation of Zn dendrites involves electrode modification. In this study, hollow nitrogen‐doped carbon spheres (HNCS) are synthesized and used as electrodes to regulate Zn deposition in Zn‐based flow batteries. The electrochemical performance of HNCS reveals
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Phosphorescence Properties of Boron/Bismuth Hybrid Conjugated Materials Chem. Asian J. (IF 4.1) Pub Date : 2024-03-01 Yohei Adachi, Shota Terao, Yusuke Kanematsu, Joji Ohshita
By introducing main‐group elements such as boron and bismuth to π‐conjugated systems, it is possible to modify the optical properties of π‐conjugated materials through orbital interactions between the orbital on the elements and π/π*‐orbitals, and the heavy atom effect. Moreover, bismuth, which is the heaviest stable element, induces a significant heavy atom effect, making organobismuth compounds promising
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Front Cover: Circularly Polarized Luminescence from Schiff‐base [4]Helicene Boron Complexes (Chem. Asian J. 4/2024) Chem. Asian J. (IF 4.1) Pub Date : 2024-02-29 Masahiro Ikeshita, Shinya Watanabe, Seika Suzuki, Maho Kitahara, Yoshitane Imai, Takashi Tsuno
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Benzannulated Double Aza[9]helicenes: Synthesis, Structures, and (Chir)optical Properties Chem. Asian J. (IF 4.1) Pub Date : 2024-02-29 Yusuke Matsuo, Masayuki Gon, Kazuo Tanaka, Shu Seki, Takayuki Tanaka
A benzannulated double aza[9]helicene 1 was successfully synthesized via a one‐pot oxidative fusion reaction. 1 was derivatized to N‐alkylated double aza[9]helicene 1‐Et and 1‐Bu, whose structures were determined by X‐ray diffraction analysis. 1‐Et and 1‐Bu exhibited red‐shifted absorption and fluorescence spectra compared to single aza[9]helicene. The double aza[9]helicenes were expected to have two
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Direct C–H Sulfuration: Synthesis of Disulfides, Dithiocarbamates, Xanthates, Thiocarbamates and Thiocarbonates Chem. Asian J. (IF 4.1) Pub Date : 2024-02-29 Qiao Sun, Yuan Xu, Liu Yang, Chun-Ling Zheng, Guowei Wang, Hai-Bo Wang, Zheng Fang, changsheng wang, Kai Guo
In light of the important biological activities and widespread applications of organic disulfides, dithiocarbamates, xanthates, thiocarbamates and thiocarbonates, the continual persuit of efficient methods for their synthesis remains crucial. Traditionally, the preparation of such compounds heavily relied on intricate multi‐step syntheses and the use of highly prefunctionalized starting materials.
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Recent Advancements on Sustainable Electrochemical Water Splitting Hydrogen Energy Applications Based on Nanoscale Transition Metal Oxide (TMO) Substrates Chem. Asian J. (IF 4.1) Pub Date : 2024-02-28 Mohsin Saeed, Umer Shahzad, Hadi M. Marwani, Abdullah M. Asiri, Shujah ur Rehman, Raed H. Althomali, Mohammed M. Rahman
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Miquelianin: primary antioxidant power and Mpro SARS‐CoV‐2 non‐covalent inhibition capabilities from computational investigations Chem. Asian J. (IF 4.1) Pub Date : 2024-02-28 Maciej Spiegel, Mario Prejanò, Nino Russo, Tiziana Marino
The antioxidant power of quercetin‐3‐O‐glucuronide (miquelianin) has been studied, at the density functional level of theory, in both lipid‐like and aqueous environments. In the aqueous phase, the computed pKa equilibria allows the identification of the neutral and charged species present in solution that can react with the •OOH radical. The Hydrogen Atom Transfer (HAT), Single Electron Transfer (SET)
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Unlocking High-Current Performance in Silicon Anode: Synergistic Phosphorus Doping and Nitrogen-Doped Carbon Encapsulation to Enhance Lithium Diffusivity Chem. Asian J. (IF 4.1) Pub Date : 2024-02-27 Arief Muhammad Firdaus, Naufal Hanif Hawari, Celfi Gustine Adios, Paramadina Masihi Nasution, Erwin Peiner, Hutomo Suryo Wasisto, Afriyanti Sumboja
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Pd-Catalyzed Oxidative C−H Arylation of (Poly)fluoroarenes with Aryl Pinacol Boronates and Experimental and Theoretical Studies of its Reaction Mechanism Chem. Asian J. (IF 4.1) Pub Date : 2024-02-27 Yudha P. Budiman, Miftahussurur Hamidi Putra, Muhammad R. Ramadhan, Raiza Hannifah, Christian Luz, Ilham Z. Ghafara, Rustaman Rustaman, Engela E. Ernawati, Tri Mayanti, Axel Groß, Udo Radius, Todd B. Marder
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A Computational Perspective on the Reactivity of π-spacers in Self-Immolative Elimination Reactions Chem. Asian J. (IF 4.1) Pub Date : 2024-02-26 Daniele Padula
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On the Existence of Pnictogen Bonding Interactions in As(III) S-Adenosylmethionine Methyltransferase Enzymes Chem. Asian J. (IF 4.1) Pub Date : 2024-02-26 Rosa M. Gomila, Antonio Frontera
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Strategic Insertion of Heavy Atom to Tailor TADF OLED Material for the Development of Type I Photosensitizing Catalytic Red Emissive Assemblies Chem. Asian J. (IF 4.1) Pub Date : 2024-02-26 Manpreet Singh, Manoj Kumar, Vandana Bhalla
The work presented in the manuscript describes a simple strategy for transforming thermally activated delayed fluorescent organic light‐emitting diodes (TADF OLEDs) compound 10‐(dibenzo[a,c]phenazin‐11‐yl)‐10H‐phenoxazine (DPZ‐PXZ) into type I photosensitizer 10‐(dibenzo[a,c]phenazin‐11‐yl)‐10H‐phenothiazine (DPZ‐PHZ) by strategically introducing sulfur atom in the photosensitizing core. The synthesized
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Boosting the Electrocatalytic Water Splitting Performance Using Hydrophilic Metal-Organic Framework Chem. Asian J. (IF 4.1) Pub Date : 2024-02-25 Munzir Suliman, Fatima Alarfaj, Muhammad Usman, Khaled M. AlAqad, Mohamed A. Hussein, Mahmoud M. Abdelnaby
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Reactions of Heteroallenes with Salan-based Ti(IV) Complexes: A Joint Experimental and Computational Study Chem. Asian J. (IF 4.1) Pub Date : 2024-02-25 Joana Hipólito, Ricardo Meyrelles, Boris Maryasin, Luis G. Alves, Ana M. Martins
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Anodization as a scalable nanofabrication method to engineer mechanobactericidal nanostructures on complex geometries Chem. Asian J. (IF 4.1) Pub Date : 2024-02-25 Anindo Roy, Sravan Reddy Kolipyak, Kaushik Chatterjee
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Stimuli-triggered Self-Assembly of Gold Nanoparticles: Recent Advances in Fabrication and Biomedical Applications Chem. Asian J. (IF 4.1) Pub Date : 2024-02-25 Yan Zhao, Chaoxiang Cui, Guohua Fan, Haibin Shi
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Directionality of Halogen-Bonds: Insights from 2D Energy Decomposition Analysis Chem. Asian J. (IF 4.1) Pub Date : 2024-02-23 Barbara Herrmann, Dennis Svatunek
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Visible Light-Induced Metal-free Arylation of Coumarin-3-carboxylates with Arylboronic Acids Chem. Asian J. (IF 4.1) Pub Date : 2024-02-22 Swarnayu Banik, Aita Saikiran, Prathyusha Permula, K. S. Srivishnu, B. Sridhar, B. V. Subba Reddy
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Sodium-Mediated Reductive C−C Bond Cleavage Assisted by Boryl Groups Chem. Asian J. (IF 4.1) Pub Date : 2024-02-22 Mizuki Fukazawa, Fumiya Takahashi, Takashi Kurogi, Hideki Yorimitsu
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Direct Through-Space Substituent-π Interactions in Noncovalent Arene–Fullerene Assemblies Chem. Asian J. (IF 4.1) Pub Date : 2024-02-22 Yoshifumi Hashikawa, Yasujiro Murata
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Advanced Functionalized Nanoclusters (Cu, Ag, and Au) as Effective Catalyst for Organic Transformation Reactions Chem. Asian J. (IF 4.1) Pub Date : 2024-02-22 Parveen Kumar, Meena Nemiwal
A considerable amount of research has been carried out in recent years on synthesizing metal nanoclusters (NCs), which have wide applications in the field of optical materials with non‐linear properties, bio‐sensing, and catalysis. Aside from being structurally accurate, the atomically precise NCs possess well‐defined compositions due to significant tailoring, both at the surface and the core, for
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Zinc Doping Induces Enhanced Thermoelectric Performance of Solvothermal SnTe Chem. Asian J. (IF 4.1) Pub Date : 2024-02-21 Lijun Wang, Xiao-Lei Shi, Lvzhou Li, Min Hong, Bencai Lin, Pengcheng Miao, Jianning Ding, Ningyi Yuan, Shuqi Zheng, Zhi-Gang Chen
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An Isolable THF‐coordinated Dialkylgermanone Chem. Asian J. (IF 4.1) Pub Date : 2024-02-21 Kazuma Oshima, Ryo Kobayashi, Kengo Sakamoto, Kenji Yoza, Shintaro Ishida, Takeaki Iwamoto
A stable dialkylgermanone was generated by mixing a solid of the corresponding dialkylgermylene and gaseous N2O. While the dialkylgermanone is marginally persistent in solution and gradually converts to its head‐to‐tail dimer at room temperature, the addition of THF to the dialkylgermanone provided an isolable THF‐coordinated dialkylgermanone. The THF‐coordinated dialkylgermanone reacts with H2O, THF
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Alkoxylated Fluoranthene-Fused [3.3.3]Propellanes: Facile Film Formation against High π-Core Content Chem. Asian J. (IF 4.1) Pub Date : 2024-02-21 Kenichi Kato, Yuta Uchida, Tomoya Kaneda, Tomoki Tachibana, Shunsuke Ohtani, Tomoki Ogoshi
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Solid-State Emissive Pillar[6]arene Derivative Having Alternate Methylene and Nitrogen Bridges Chem. Asian J. (IF 4.1) Pub Date : 2024-02-21 Shunsuke Ohtani, Kazeto Nakaguchi, Kenichi Kato, Tomoki Ogoshi
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Advancements in Olive‐derived Carbon: Preparation Methods and Sustainable Applications Chem. Asian J. (IF 4.1) Pub Date : 2024-02-20 A.H. Shabi, Yuda Prima Hardianto, Syed Shaheen Shah, Fatima Omar Al-Qwairi, Mostafa M. Mohamed, M. Nasiruzzaman Shaikh, Atif Saeed Alzahrani, Md. Abdul Aziz
In the realm of material science, carbon materials, especially olive‐derived carbon (ODC), have become vital due to their sustainability and diverse properties. This review examines the sustainable extraction and use of ODC, a carbohydrate‐rich by‐product of olive biomass. We focus on innovative preparation techniques like pyrolysis, crucial for enhancing ODC's microstructure and surface properties
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Design, Synthesis, and Characterization of Novel Styryl Dyes as Fluorescent Probes for Tau Aggregate Detection in Vitro and in Cells Chem. Asian J. (IF 4.1) Pub Date : 2024-02-20 Withsakorn Sangsuwan, Kriangsak Faikhruea, Kotchakorn Supabowornsathit, Don Sangsopon, Praewphan Ingrungruanglert, Hathaichanok Chuntakaruk, Napatsaporn Nuntavanotayan, Kittiporn Nakprasit, Nipan Israsena, Thanyada Rungrotmongkol, Pitak Chuawong, Tirayut Vilaivan, Chanat Aonbangkhen
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Ce‐doped TiO2 fabricated glassy carbon electrode for efficient hydrogen evolution reaction in acidic medium Chem. Asian J. (IF 4.1) Pub Date : 2024-02-20 Md. Nurnobi Islam, Md Mosaraf Hossain, Shrikant S. Maktedar, Mostafizur Rahaman, Mohammad Atiqur Rahman, Mohammad A. Hasnat
The quest for sustainable and clean energy sources has intensified research on the Hydrogen Evolution Reaction (HER) in recent decades. In this study, we present a novel Ce‐doped TiO2 catalyst synthesized through the sol‐gel method, showcasing its potential as a superior electrocatalyst for HER in an acidic medium. Comprehensive characterization through X‐ray diffraction (XRD), X‐ray photoelectron
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Template Assisted One-Pot Synthesis of [2], Linear [3], and Radial [4]Catenane via Click Reaction Chem. Asian J. (IF 4.1) Pub Date : 2024-02-19 Mana Bhanjan Podh, Radhakrishna Ratha, Chandra Shekhar Purohit
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Non-Linear Optical Activity of Chiral Bipyrimidine-Based Thin Films Chem. Asian J. (IF 4.1) Pub Date : 2024-02-14 Prescillia Nicolas, Stephania Abdallah, Ahmet Dok, Yovan de Coene, Olivier Jeannin, Nathalie Bellec, Jean-Pierre Malval, Thierry Verbiest, Koen Clays, Stijn Van Cleuvenbergen, Belkiz Bilgin-Eran, Huriye Akdas-Kiliç, Franck Camerel
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Carbon-Sulfur Bond Cleavage in Methanesulfonate on Diorganotin Quinaldate Platform – Synthesis and Characterization of [(n-Bu2SnL)2SO4] Chem. Asian J. (IF 4.1) Pub Date : 2024-02-14 Priyanka Chauhan, Aishwarya Chauhan, Ravi Shankar
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Current Development of Lanthanide Complexes for Biomedical Applications Chem. Asian J. (IF 4.1) Pub Date : 2024-02-13 Mengfei Wang, Yuichi Kitagawa, Yasuchika Hasegawa
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Multiple Force-Triggered Downconverted and Upconverted Emission in Polymers Containing Diels-Alder Adducts Chem. Asian J. (IF 4.1) Pub Date : 2024-02-09 Guohua Zhu, Qiaoyu Zhang, Tianjun Yu, Jinping Chen, Rui Hu, Guoqiang Yang, Yi Zeng, Yi Li
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The dopamine D2 receptors antagonist Veralipride inhibits carbonic anhydrases: solution and crystallographic insights on human isoforms Chem. Asian J. (IF 4.1) Pub Date : 2024-02-09 Andrea Angeli, Marta Ferraroni, Clemente Capasso, Claudiu T. Supuran
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Cu/MgO Reverse Water Gas Shift Catalyst with Unique CO2 Adsorption Behaviors Chem. Asian J. (IF 4.1) Pub Date : 2024-02-08 Ding-Huei Tsai, Tung-Ta Wu, Hung-Chin Lin, Lu-Yu Chueh, Kun-Han Lin, Wen-Yueh Yu, Yung-Tin Pan
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Defect Engineering in GO Membranes – Tailoring Size and Oxidation Degree of Nanosheet for Enhanced Pore Channels Chem. Asian J. (IF 4.1) Pub Date : 2024-02-08 Nan Li, Weihao Xue, Yu Han, Bo Zhu, Jinman Wu, Zhiwei Xu