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Mechanochromic hydrogel fibers with multiple fluorescent colors Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-18 Bo Xu, Jin Yang, Yinghe Yang, Jiping Yang, Zhijian Wang
Mechanochromic polymers can change their color in reimsponse to external force and have shown promising applications in stress sensing and failure warning. They are usually obtained as thin film or bulky specimen. The mechanochromic fibers, which could be used to make smart fabrics, have been seldom reported due to the lack of efficient fabrication techniques. In this work, we report a general method
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Mesoionic N-Heterocyclic Olefins as Initiators for the Lewis Pair Polymerization of Epoxides Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-18 Iris Haug, Justus Reitz, Célia Ziane, Michael R. Buchmeiser, Max M. Hansmann, Stefan Naumann
Mesoionic N-heterocyclic olefins (mNHOs) have recently emerged as a novel class of highly nucleophilic and super-basic σ-donor compounds. Making use of these properties in synthetic polymer chemistry, it is shown that a combination of a specific mNHO and a Mg-based Lewis acid (magnesium bis(hexamethyldisilazide), Mg(HMDS)2) delivers poly(propylene oxide) in quantitative yields from the polymerization
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Design Synthesis, and Acid-Responsive Disassembly of Shell-Sheddable Block Copolymer Labeled with Benzaldehyde Acetal Junction Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-18 Brandon Andrade-Gagnon, Sofia Nieves Casillas-Popova, Arman Moini Jazani, Jung Kwon Oh
Smart nanoassemblies degradable through the cleavage of acid-labile linkages have attracted significant attention because of their biological relevance found in tumor tissues and cancer cells. Despite their high potential for tumor-targeting drug delivery exhibiting controlled/enhanced drug release, systematic understanding on their structural factors that affect the pH sensitivity of these functionalities
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Semi-transparent Luminescent Solar Concentrators based on Intramolecular Energy Transfer in Polyurethane Matrices Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-14 Elisavet Tatsi, Matteo De Marzi, Luca Mauri, Alessia Colombo, Chiara Botta, Stefano Turri, Claudia Dragonetti, Gianmarco Griffini
Luminescent solar concentrators (LSCs) are spectral conversion devices offering interesting opportunities for integration of photovoltaics into the built environment and portable systems. The Förster-resonance energy transfer (FRET) process can boost the optical response of LSCs by reducing energy losses typically associated to non-radiative processes occurring within the device under operation. In
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Recent Advances in Controlled Production of Long‐Chain Branched Polyolefins Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-16 Arezoo Dashti, Mostafa Ahmadi
Polyolefins, composed of carbon and hydrogen atoms, dominate global polymer production. This stems from the wide range of physical and mechanical properties that various polyolefins can cover. Their versatile properties are largely tuned by chain microstructure, including molar mass distribution, comonomer content, and long‐chain branching (LCB). Specifically, LCB imparts unique characteristics, notably
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Viscosity of Suspensions of Strongly Bonded Spherical Particles of Nickel‐Manganese‐Cobalt Mixed Oxides (NMC) in Molten Poly(Ethylene Carbonate) for Batteries. Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-14 Augustin Flament, Melinda Desse, Pierre Bernard, Christian Carrot
Ionically conductive polymers highly filled with active materials, such as metal oxides are increasingly studied for their potential use in all solid‐state batteries. They offer the desirable processing ease of polymers for mass production despite interfacial issues that remain to be solved. In this study, it is shown that spherical particles of transition metal oxides can be introduced in co‐polymers
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A Solar Evaporator Based on Polypyrrole Coated 3D Carbon Nanotube Materials for Efficient Solar‐Driven Vapor Generation Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-14 Hao Xun, Chuang Wang, Zhaohui Yang, Xiaohua Zhang
We fabricate highly porous light absorbers based on polypyrrole (PPy)‐coated carbon nanotube (CNT). Carbon nanotube sponge (CNTS) or carbon nanotube array (CNTA) with three‐dimensional (3D) network structure is the framework of porous light absorbers. Both PPy@CNTS and PPy@CNTA composites exhibit excellent light absorption of full solar spectrum. The CNTS and CNTA with porous structures have extremely
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Quasi‐chromophores Segregated by Single‐chain Nanoparticles of Fluorinated Zwitterionic Random Copolymers Showing Remarkably Enhanced Fluorescence Emission Capable of Fluorescent Cell Imaging Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-13 Yongming Zeng, Tianchi Xu, Weizhi Chen, Jianglin Fang, Dongzhong Chen
Organic and polymer fluorescent nanomaterials have been a frontier research focus. Here in this work, a series of fluorinated zwitterionic random copolymers end‐attached with a quasi‐chromophoric group of pyrene or tetraphenylethylene (TPE) have been well synthesized via atom transfer radical polymerization with activators regenerated by electron transfer (ARGET ATRP). Those random copolymers with
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Rubber Oxygenase Degradation Assay by UV‐labelling and Gel Permeation Chromatography Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-13 Vico K. B. Adjedje, Yannick L. Wolf, Martin J. Weissenborn, Wolfgang H. Binder
A versatile and robust end‐group derivatization approach using oximes has been developed for the detection of oxidative degradation of synthetic polyisoprenes and polybutadiene. This method demonstrates broad applicability, effectively monitoring degradation across a wide molecular weight range through UV‐detection via gel permeation chromatography. Importantly, it enables the effective monitoring
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Non‐Isocyanate Polyurethane Segmented Copolymers from Bis‐Carbonylimidazolides Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-12 Jose I. Sintas, Ren H. Bean, Rui Zhang, Timothy E. Long
Bis‐carbonylimidazolide (BCI) functionalization enabled an efficient synthetic strategy to generate high molecular weight segmented non‐isocyanate polyurethanes (NIPUs). Melt phase polymerization of ED‐2003 Jeffamine®, 4,4′‐methylenebis(cyclohexylamine), and a BCI monomer that mimics a 1,4‐butanediol chain extender enabled polyether NIPUs that contain varying concentrations of hard segments ranging
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Visible Light-Regulated Ring-Opening Polymerization of Lactones by Employing Indigo as a Photoacid Catalyst Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-12 Pan Sun, Zixuan Li, Xun Zhang, Yun Liao, Saihu Liao
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Porous Anisometric PNIPAM Microgels ‐ Tailored Porous Structure and Thermal Response Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-10 Lea Steinbeck, Hanna J. M. Wolff, Maximilian Middeldorf, John Linkhorst, Matthias Wessling
The porous structure of microgels significantly influences their properties and, thus, their suitability for various applications, in particular as building blocks for tissue scaffolds. Porosity is one of the crucial features for microgel‐cell interactions and significantly increases the cells' accumulation and proliferation. Consequently, tailoring the porosity of microgels in an effortless way is
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Skin-Friendly Flexible Ultraviolet Detectors Based on Reversibly Deformable Worm-Like Polymer Nanoparticles Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-08 Jianing Han, Zichao Deng, Rui Wang, Zhefeng Liu, Yalan Sun, Aihua Chen
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4D Fabrication of Two-Way Shape Memory Polymeric Composites by Electrospinning and Melt Electrowriting Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-08 Chiara Pasini, Zhander Vohr Soreño, Dennis Schönfeld, Thorsten Pretsch, Gissela Constante, Ilia Sadilov, Leonid Ionov
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Effect of Oligomer Addition on Tube Dilation in Polymer Nanocomposite Melts Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-07 Yi Feng, Ruhao Li, Christopher Mbonu, Pinar Akcora
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Designing a New Class of Mechanophoric Polymer Based on Epoxy-Functionalized Rhodamine Derivative Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-07 Swadhin Chakraborty, Koushik Bhattacharya, Soumyadip Choudhury, Nikhil K. Singha
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Dynamic Thermosetting Resins with Synergistic Enhanced Strength and Toughness through Combination with Rigid and Soft Microdomains Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-07 Yinzhou Guo, Tiantian Shu, Yihan Wang, Chenhui Cui, Qinghao Zhou, Qiang Zhang, Yilong Cheng, Zhishen Ge, Gang Chen, Yanfeng Zhang
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A Molecular Rheology Dynamics Study on 3D Printing of Liquid Crystal Elastomers Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-06 Senay Ustunel, Harsh Pandya, Marianne E. Prévôt, Gisele Pegorin, Faeze Shiralipour, Rajib Paul, Robert J. Clements, Fardin Khabaz, Elda Hegmann
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A Preliminary Study of Thermosets from Epoxy Resins Made Using Low-Toxicity Furan-Based Diols Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-05 Olena Shafranska, Catherine Sutton, Deep Kalita, Prakash Kannaboina, Sandip Tiwari, Mukund P. Sibi, Dean C. Webster
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Precisely Controlled Polymerization of Two-Dimensional Conducting Polymers in Quasi-Liquid Layer Enables Ultrahigh Sensing Performance Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-04 Yucheng Zhu, Mengzhen Wei, Xinlei Ma, Hui Ma, Ruoqi Chen, Huanrong Zhang, Xusheng Wang, Junhui Ji, Mianqi Xue
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A Unique Temperature-Induced Reverse Supramolecular Chirality-Assisted Gel-to-Gel Transition Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-04 Dinesh Kumar Duraisamy, Samala Murali Mohan Reddy, Puchalapalli Saveri, Abhijit P. Deshpande, Ganesh Shanmugam
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Revolutionizing Cancer Treatment: Biopolymer-Based Aerogels as Smart Platforms for Targeted Drug Delivery Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-03-02 Hala M. Alkhalidi, Amerh Aiad Alahmadi, Waleed Y. Rizg, Esam Bashir Yahya, Abdul Khalil H.P.S., Rayan Y. Mushtaq, Moutaz Y. Badr, Awaji Y. Safhi, Khaled M. Hosny
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Scalable Fabrication of Structurally Stable Polymer Film with Excellent UV-Shielding, Fluorescent, and Antibacterial Capabilities Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-27 Kaiyuan Shen, Hongchen Liu, Changjing Qiu, Mengzhen Yuan, Zhishan Chen, Haisong Qi
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Effects of Structurally Different Tertiary Amines on the Properties of Quaternized Anionic Exchange Membranes Potentially Applicable for Water Electrolysis Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-27 Andrea Roggi, Gabriele Agonigi, Claudio Resta, Antonio Filpi, Elisa Martinelli, Elisa Guazzelli
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Access to 2,4-Disubstituted Pyrrole-Based Polymer with Long-Wavelength and Stimuli-Responsive Properties via Copper-Catalyzed [3+2] Polycycloaddition Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-26 Lingna Wang, Jianbo Zhang, Chunmei Li, Wanbin Dang, Wei Guo, Junjian Xie, Fengtao Zhou, Qiuyu Zhang
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Powders to Thin Films: Advances in Conjugated Microporous Polymer Chemical Sensors Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-26 Saurabh Kumar Rajput, Venkata Suresh Mothika
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Nano‐Micron Combined Hydrogel Microspheres: Novel Answer for Minimal Invasive Biomedical Applications Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-24 Jiacheng Liu, Chengcheng Du, Hong Chen, Wei Huang, Yiting Lei
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Stimuli-Responsive Polymers for Engineered Emulsions Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-23 Abhishek Rajbanshi, Eleanor Hilton, Cécile A. Dreiss, Darragh Murnane, Michael T. Cook
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Direct C–H Arylation Derived Ternary D–A Conjugated Polymers: Effects of Monomer Geometries, D/A Ratios, and Alkyl Side Chains on Photocatalytic Hydrogen Production and Pollutant Degradation Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-20 Zhao‐Qi Shen, Guang Zhang, Kai Yang, Yu‐Jie Zhang, Hao Gong, Guangfu Liao, Shi‐Yong Liu
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N, S‐Codoped Carbon Dots‐Based Reusable Solvatochromic Organogel Sensors for Detecting Organic Solvents Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-20 Gwajeong Jeong, Taewook Kim, Seong Dae Park, Myong Jae Yoo, Chan Ho Park, Hyunseung Yang
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Effect of Lignin Structure Characteristics on the Performance of Lignin Based Phenol Formaldehyde Adhesives Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-20 Xinwen Xu, Haiming Li, Xing Wang, Haiqiang Shi, Meihong Niu, Yongchao Zhang, Zhiwei Wang, Yanzhu Guo
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Antimony-Based Halide Perovskite Nanoparticles as Lead-Free Photocatalysts for Controlled Radical Polymerization Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-13 Yifan Zhu, Jiahui Zhang
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Ionic Thermoelectric Generators in Vertical and Planar Topologies Based on Fluorinated Polymer Hybrid Materials with Ionic Liquids Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-17 Nelson Pereira, Luis Afonso, Manuel Salado, Carmen R. Tubio, Daniela M. Correia, Carlos M. Costa, Senentxu Lanceros-Mendez
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Clickable Polymerization-Induced Emission Luminogens Toward Color-Tunable Modification of Non-Traditional Intrinsic Luminescent Polymers Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-16 Xiao-Li Sun, Hong Xue, Xi-Yao Gu, De-Shan Li, Hang Xiao, Wen-Ming Wan
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Chemical Recycling and Physical Tuning of Necklace-Shaped Polydimethylsiloxanes Bearing Anthracene Dimer Units Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-16 Atsuro Mori, Agamoni Pathak, Satoshi Watanabe, Masashi Kunitake
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Novel Fluorinated Anion Exchange Membranes Based on Poly(Pentafluorophenyl-Carbazole) with High Ionic Conductivity and Alkaline Stability for Fuel Cell Applications Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-15 Qijia Li, Liming Wu, Yang Pang, Binghui Liu, Xuanbo Zhu, Chengji Zhao
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1,3,4,5-Tetrasubstituted Poly(1,2,3-triazolium) Obtained through Metal-Free AA+BB Polyaddition of a Diazide and an Activated Internal Dialkyne Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-13 Rania Akacha, Imen Abdelhedi-Miladi, Anatoli Serghei, Hatem Ben Romdhane, Eric Drockenmuller
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The Isothermal Melting Kinetics of Ultra-High Molecular Weight Polyethylene Crystals Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-12 Jianwei Xue, Yaguang Lu, Binghua Wang, Jingbo Chen, Changyu Shen, Bin Zhang
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Hyperbranched Polymer Induced Antibacterial Tree-Like Nanofibrous Membrane for High Effective Air Filtration Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-09 Weitao Zhao, Mengxuan Wang, Ying Yao, Zhongqiu Cheng, Yaxinru Shen, Yufan Zhang, Jin Tao, Jiaqing Xiong, Hongmei Cao, Desuo Zhang
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On the Swelling of Polymer Network Strands Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-07 Michael Lang, Reinhard Scholz
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3D Printing of Capacitive Pressure Sensors with Tuned Wide Detection Range and High Sensitivity Inspired by Bio-Inspired Kapok Structures Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-02-07 Qingxin Jin, Chengyun Wang, Han Wu, Xin Luo, Jiaqi Li, Guangmeng Ma, Yu Li, Chunyi Luo, Fawei Guo, Yu Long
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Effect of Amino Acid Types on the Mechanical and Antimicrobial Properties of Amino Acid-Based Polyionic Liquid Hydrogels Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-01-30 Jingying Fan, Xiaoling He, Xuanping Zhou, Saisai Li, Yuqing Yang
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MaDDOSY (Mass Determination Diffusion Ordered Spectroscopy) using an 80 MHz Bench Top NMR for the Rapid Determination of Polymer and Macromolecular Molecular Weight Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-01-30 Owen Tooley, William Pointer, Rowan Radmall, Mia Hall, Valentin Beyer, Kieran Stakem, Thomas Swift, James Town, Tanja Junkers, Paul Wilson, Daniel Lester, David Haddleton
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Preparation of Block Copolymer Self-Assemblies via Pisa in a Non-Polar Medium Based on RCMP Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-01-29 Yichao Zheng, Hiroshi Niino, Shunsuke Chatani, Atsushi Goto
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Relief of Residual Stress in Bulk Thermosets in the Glassy State by Local Bond Exchange Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-01-27 Kangning Wu, Dongxu An, Zhuolin Zhang, Ge Zhao, Chenhui Cui, Fusheng Zhou, Jianying Li
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Photocuring 3D Printing of Hydrogels: Techniques, Materials, and Applications in Tissue Engineering and Flexible Devices Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-01-25 Guoqiang Lu, Ruifen Tang, Jun Nie, Xiaoqun Zhu
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Polar Molecules Regulating the Regio- and Stereoselectivity of Polymerization of Conjugated Dienes Catalyzed by CGC-Type Rare-Earth Metal Catalysts Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-01-23 Zhijie Fu, Chuang Song, Chongan Chen, Yuanxia Qi, Jingting Pei, Yuwei Chen, Jie Zheng, Yanan Zhao, Yi Luo, Xiaofang Li
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Polymer Waste Valorization into Advanced Carbon Nanomaterials for Potential Energy and Environment Applications Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-01-20 Akshata Pattanshetti, Amruta Koli, Rohant Dhabbe, Xiao-Ying Yu, Radha Kishan Motkuri, Vijay D. Chavan, Deok-kee Kim, Sandip Sabale
The rise in universal population and accompanying demands have directed towards an exponential surge in the generation of polymeric waste. The estimate predicts that world-wide plastic production will rise to approximately 590 million metric tons by 2050, whereas 5000 million more tires will be routinely abandoned by 2030. Handling this waste and its detrimental consequences on the Earth's ecosystem
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Constructing Novel High Dielectric Constant Polyimides Containing Dipolar Pendant Groups with Enhanced Orientational Polarization Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-01-15 Yadong Tang, Wenhan Xu, Hongyan Yao, Hao Qin, Zhenhua Jiang, Yunhe Zhang
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Sprayable Zwitterionic Antibacterial Hydrogel With High Mechanical Resilience and Robust Adhesion for Joint Wound Treatment Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-01-18 Qinsheng Hu, Yangrui Du, Yangjing Bai, Dandan Xing, Shiying Lang, Kaijun Li, Xinyun Li, Yong Nie, Gongyan Liu
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High-Performance Piezoelectric Nanogenerator of BTO-PVDF Nanofibers for Wearable Sensing Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-01-17 Jiang Jiang, Lingyu Wan, Liuyan Li, Ping Li
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The Recent Advances of Polymer–POSS Nanocomposites With Low Dielectric Constant Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-01-17 Li Miao, Lingling Zhan, Shenglong Liao, Yang Li, Tian He, Shouchun Yin, Lianbin Wu, Huayu Qiu
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Fast and Scalable Synthetic Route to Densely Grafted, Branched Polystyrenes and Polydienes via Anionic Polymerization Utilizing P2VP as Branching Point Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-01-17 Max G. Schußmann, Lukas Kreutzer, Valerian Hirschberg
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Poly(dehydroalanine)-Based Hydrogels as Efficient Soft Matter Matrices for Light-Driven Catalysis Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-01-17 Tolga Çeper, Marcel Langer, Nikita Vashistha, Benjamin Dietzek-Ivanšić, Carsten Streb, Sven Rau, Felix H. Schacher
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Porous Poly(ionic Liquid) Membrane with Metal Nanoparticle Gradient: A Smart Actuator for Visualizing Chemical Reactions Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-01-17 Xue-Jing Zhao, Si-Hua Liu, Jian-Ke Sun
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Polyacetylene-Based Asymmetric Bicyclic Polymer by Blocking-Cyclization Technique Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-01-16 Cuihong Ma, Hao Wang, Ruyi Sun, Xiaojuan Liao, Huijing Han, Meiran Xie
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Aliphatic Hyperbranched Polycarbonates Solid Polymer Electrolytes with High Li-Ion Transference Number for Lithium Metal Batteries Macromol. Rapid Commun. (IF 4.6) Pub Date : 2024-01-16 Chengliang Wang, Xu Zhang, Xiaofei Sun, Yan Zhang, Qingfu Wang, Jingjiang Sun