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Stereoselective access to β-gem-difluorinated alcohols through enzymatic reduction Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-16 Lucas Bacheley, Julien Boutet, Gérard Guillamot, Pierre Gilles, Juliette Martin, Phannarath Phansavath, Virginie Ratovelomanana-Vidal
We report here a mild and efficient process to access diversely functionalized enantioenriched b-gemdifluorinated (S)-alcohols by using biocatalytic reduction in > 99% yield and enantiomeric excesses ranging from 96% to >99%. This novel approach involves enzymatic reduction of α-gem-difluorinated heterocyclic and carbocyclic ketone derivatives as well as an acyclic gem-difluorinated β-ketosulfone and
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Manganese-Mediated Electrooxidative Ring-Opening Azidation of Cyclobutanol Derivatives with TMSN3 Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-16 Wenchao Gao, Jie Yang, Yong Teng, Wendian Li, Wenguang Li, Ting Li
A Mn-electrocatalytic ring-opening azidation of tert-cyclobutanols has been developed. The regioselective method is applicable for the azidation of a diverse array of cyclobutanols to provide γ-azido ketones in 23-91% yields under chemical oxidants-free reaction conditions. Detailed mechanistic studies suggest the process of Mn-mediated alkoxy radical generation followed by β-scission to form carbon-centered
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Key Role of CO Coverage for Chain Growth in Co-Based Fischer–Tropsch Synthesis ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Konstantijn T. Rommens, G.T. Kasun Kalhara Gunasooriya, Mark Saeys
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Plasma Catalysis for Hydrogen Production: A Bright Future for Decarbonization ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Ni Wang, Hope O. Otor, Gerardo Rivera-Castro, Jason C. Hicks
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Photoenzymatic Redox-Neutral Radical Hydrosulfonylation Initiated by FMN ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Linye Jiang, Dannan Zheng, Xiaoyang Chen, Dong Cui, Xinyu Duan, Zhiguo Wang, Jingyan Ge, Jian Xu
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Catalytic Consequences of Protons in Methanol Oxidative Dehydrogenation on Molybdenum-Based Polyoxometalate Clusters ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Guangming Cai, Ya-Huei Cathy Chin
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Coupling Waste Plastic Upgrading and CO2 Photoreduction to High-Value Chemicals by a Binuclear Re–Ru Heterogeneous Catalyst ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Mei Li, Shengbo Zhang
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Photocatalytic Regeneration of Reactive Cofactors with InP Quantum Dots for the Continuous Chemical Synthesis ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Indra Narayan Chakraborty, Vanshika Jain, Pradyut Roy, Pawan Kumar, Chathakudath P. Vinod, Pramod P. Pillai
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Synergistic Organoboron/Palladium Cocatalyzed Dehydrative Couplings of Azoles with Allylic Alcohols: A Combined Experimental and Computational Mechanistic Investigation ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Matthew T. Zambri, Teh Ren Hou, Sofia Jdanova, Mark S. Taylor
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Construction of Diazo Compounds via Catalytic [3 + 2] Annulation of Vinyldiazoacetates and Their Synthetic Applications ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Ming Bao, Diana Victoria Navarrete Carriola, Daniel Wherritt, Michael P. Doyle
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Steric Effects on the Oxygen Reduction Reaction with Cobalt Porphyrin Atropisomers ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Tao Liu, Haonan Qin, Yuhan Xu, Xinyang Peng, Wei Zhang, Rui Cao
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Enantioselective Synthesis of Axially Chiral Diaryl Ethers through Chiral Phosphoric Acid-Catalyzed Desymmetric Acylation with Azlactones ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Jiawei Xu, Wei Lin, Hanliang Zheng, Xin Li
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CsPbBr3 Perovskite Polyhedral Nanocrystal Photocatalysts for Decarboxylative Alkylation via Csp3–H Bond Activation of Unactivated Ethers ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Soumya Mondal, Souvik Banerjee, Suman Bera, Subal Mondal, Siba P. Midya, Rajkumar Jana, Rakesh Kumar Behera, Ayan Datta, Narayan Pradhan, Pradyut Ghosh
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Sensitized and Self-Sensitized Photocatalytic CO2 Reduction to HCO2– and CO under Visible Light with Ni(II) CNC-Pincer Catalysts ACS Catal. (IF 12.9) Pub Date : 2024-04-15 Sonya Y. Manafe, Nghia Le, Ethan C. Lambert, Christine Curiac, Dinesh Nugegoda, Sanjit Das, Leigh Anna Hunt, Fengrui Qu, Logan M. Whitt, Igor Fedin, Nathan I. Hammer, Charles Edwin Webster, Jared H. Delcamp, Elizabeth T. Papish
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Dinuclear Cu(I) molecular electrocatalyst for CO2-to-C3 product conversion Nat. Catal. (IF 37.8) Pub Date : 2024-04-15 Naonari Sakamoto, Keita Sekizawa, Soichi Shirai, Takamasa Nonaka, Takeo Arai, Shunsuke Sato, Takeshi Morikawa
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Visualizing the structural evolution of individual active sites in MoS2 during electrocatalytic hydrogen evolution reaction Nat. Catal. (IF 37.8) Pub Date : 2024-04-15 Teng-Xiang Huang, Xin Cong, Si-Si Wu, Jiang-Bin Wu, Yi-Fan Bao, Mao-Feng Cao, Liwen Wu, Miao-Ling Lin, Xiang Wang, Ping-Heng Tan, Bin Ren
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Catalytic Dinitrogen Reduction to Silylamines by Molybdenum Nitride Complexes Bearing a Diphenolate N-Heterocyclic Carbene Ligand ACS Catal. (IF 12.9) Pub Date : 2024-04-15 Zhaoxin Li, Chenrui Liu, Jingyi An, Xi Wang, Shaowei Hu
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Structural and Functional Analysis of Heparosan Synthase 2 from Pasteurella multocida to Improve the Synthesis of Heparin ACS Catal. (IF 12.9) Pub Date : 2024-04-15 Eduardo Stancanelli, Juno A. Krahn, Elizabeth Viverette, Robert Dutcher, Vijayakanth Pagadala, Mario J. Borgnia, Jian Liu, Lars C. Pedersen
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Nitrogen, Sulfur Co-doped Hollow Carbon-Encapsulated Cu/Co2P for Selective Oxidation Esterification of Furfurals ACS Catal. (IF 12.9) Pub Date : 2024-04-15 Yangyang Dong, Gaofeng Chen, Xiongxiong Zuo, Jiaran Li, Jia Yu, Ge Zhang, Junhua Kuang, Isil Akpinar, Li Peng, Xing Tang, Jin-Chao Dong, Lu Lin, Pengbo Lyu, Shuliang Yang, Jian-Feng Li
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Site-Selective Bimetallic Heterogeneous Nanostructures for Plasmon-Enhanced Photocatalysis of Nitrobenzene Hydrogenation ACS Catal. (IF 12.9) Pub Date : 2024-04-15 Ya-Qin Wang, Jun-Rong Zheng, Qi Liu, Yu-Qiang Shi, Hui-Jie Liu, Zheng Huang, Jun Yi, Ye Yang, Qin Kuang
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Palladium-Catalyzed Annulations via Sequential C–H Activations of C(sp2)–H/C(sp3)–H or C(sp3)–H/C(sp3)–H Bonds ACS Catal. (IF 12.9) Pub Date : 2024-04-15 Wan-Xu Wei, Mateusz Czajkowski, Yangjin Kuang, Tu-Anh V. Nguyen, Bo Qin, Martin Tomanik
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Hydrogen Peroxide as an Ideal Electron Donor for Long-Lasting Fenton Chemistry: Strong Enhancement of Fe(III) Activity by Heteroatom-Doped Nanocarbons ACS Catal. (IF 12.9) Pub Date : 2024-04-14 Yiming Sun, Peng Zhou, Minglu Sun, Yuchen Zhang, Xiao Wang, Chenying Zhou, Yang Liu, Chuanshu He, Bo Lai
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Direct characterization of interface sites in Au/TiO2 catalysts prepared using atomic layer deposition Chem Catal. Pub Date : 2024-04-15 Wang Ke, Xiangdong Qin, Yovanny Vazquez, Ilkeun Lee, Francisco Zaera
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Synthesis of C5-boryl indoles via a borane-catalyzed borylation/hydride transfer cascade Chem Catal. Pub Date : 2024-04-15 Baoquan Zhan, Jianxing Lv, Jiangyue Wu, Hua Zhang
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Stable Operation of Paired CO2 Reduction/Glycerol Oxidation at High Current Density ACS Catal. (IF 12.9) Pub Date : 2024-04-13 Attila Kormányos, Adrienn Szirmai, Balázs Endrődi, Csaba Janáky
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Generation of Sulfamoyl Radical for the Modular Synthesis of Sulfonamides ACS Catal. (IF 12.9) Pub Date : 2024-04-13 Haiping Lv, Xinzhou Chen, Xuemei Zhang, Søren Kramer, Zhong Lian
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Solar Gas-Phase CO2 Hydrogenation by Multifunctional UiO-66 Photocatalysts ACS Catal. (IF 12.9) Pub Date : 2024-04-12 Celia M. Rueda-Navarro, Zahraa Abou Khalil, Arianna Melillo, Belén Ferrer, Raúl Montero, Asier Longarte, Marco Daturi, Ignacio Vayá, Mohamad El-Roz, Virginia Martínez-Martínez, Herme G. Baldoví, Sergio Navalón
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Theoretical Insights into the Reaction Mechanism of Direct Hydrogenation of Maleic Anhydride to Produce 1,4-Butanediol on the Cu–ZnO Surface ACS Catal. (IF 12.9) Pub Date : 2024-04-12 Xinyue Guan, Yingzhe Yu, Minhua Zhang
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Practical Machine Learning-Assisted Design Protocol for Protein Engineering: Transaminase Engineering for the Conversion of Bulky Substrates ACS Catal. (IF 12.9) Pub Date : 2024-04-12 Marian J. Menke, Yu-Fei Ao, Uwe T. Bornscheuer
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Nickel-Catalyzed Deoxygenative Disulfuration of Alcohols to Access Unsymmetrical Disulfides ACS Catal. (IF 12.9) Pub Date : 2024-04-11 Xiyao Chen, Wen Shao, Guo-Jun Deng
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Cobalt Catalyzed Annulation of Benzimidates or NH‐Benzaldimines with Ynamides : Synthesis of 1‐Alkoxy‐ and 1‐Alkyl‐3‐Aminoisoquinolines Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-13 Isabelle Gillaizeau, Cyril NICOLAS, Elsa Anselmi, pascal retailleau, Liliane Mimoun, Hamdi Sanaa
Inexpensive cobalt‐catalyzed, pivalic acid‐assisted oxidative C‐H functionalization of benzimidates or NH‐benzaldimines with ynamides is presented, providing an access to 3‐aminoisoquinoline derivatives. The procedure is compatible with various substrates featuring alkyl, alkoxy, acyl or halogen as substituents, heteroaryl structures, and diverse ynamides. The reaction has been scaled up, with subsequent
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Organocatalyzed, Three‐Component Construction of Cyanopyrazoles Using Diazoacetonitrile Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-13 Anamika Dhami, Anuj Kumar, Kalathingal Hisana, KISHOR MOHANAN
An organocatalyzed three‐component protocol using diazoacetonitrile to access a wide range of cyanopyrazole derivatives has been reported herein. This strategy, which proceeds through a piperidine‐catalyzed Knoevenagel condensation/formal [3+2] cycloaddition/dehydrocyanation sequence, provides an efficient route to construct dicyanopyrazoles from aldehydes, malononitrile, and diazoacetonitrile regioselectively
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Copper‐Catalyzed α‐Indolmethylation of 2‐Pyridylacetates with 3‐Indoleacetic Acids via Alkylideneindolenine Intermediates Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-13 Xiaodong Tang, Chen Chen, Yongjun Chen, Jianxin Pang, Weiya Kong
This study reports the copper‐catalyzed α‐indolmethylation of 2‐pyridylacetates with 3‐indoleacetic acids. This reaction offers a approach to generating alkylideneindolenine electrophiles via the oxidative decarboxylation of 3‐indoleacetic acids. The developed reaction system demonstrates good versatility, extending beyond the indolmethylation of 2‐ pyridylacetates to include activated esters and nitroalkanes
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Stabilization of layered lithium-rich manganese oxide for anion exchange membrane fuel cells and water electrolysers Nat. Catal. (IF 37.8) Pub Date : 2024-04-12 Xuepeng Zhong, Lijun Sui, Menghao Yang, Toshinari Koketsu, Malte Klingenhof, Sören Selve, Kyle G. Reeves, Chuangxin Ge, Lin Zhuang, Wang Hay Kan, Maxim Avdeev, Miao Shu, Nicolas Alonso-Vante, Jin-Ming Chen, Shu-Chih Haw, Chih-Wen Pao, Yu-Chung Chang, Yunhui Huang, Zhiwei Hu, Peter Strasser, Jiwei Ma
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Diastereo- and Enantioselective Dearomative Reductive Aryl-Fluoroalkenylation of Indoles by Nickel Catalysis ACS Catal. (IF 12.9) Pub Date : 2024-04-11 Xinmiao Huang, Min Ou, Lixin Hong, Wenjie Qin, Yuanhong Ma
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Nickel-Based Catalysts for the Selective Monoarylation of Dichloropyridines: Ligand Effects and Mechanistic Insights ACS Catal. (IF 12.9) Pub Date : 2024-04-11 Geraldo Duran-Camacho, Douglas C. Bland, Fangzheng Li, Sharon R. Neufeldt, Melanie S. Sanford
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Double Catalytic Activity Unveiled: Synthesis, Characterization, and Catalytic Applications of Iridium Complexes in Transfer Hydrogenation and Photomediated Transformations ACS Catal. (IF 12.9) Pub Date : 2024-04-11 Laura Blanco, Andrea Uroz, Kevin Gutiérrez, Silvia Cabrera, Alba Collado, José Alemán
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Supported Catalytically Active Liquid Metal Solutions: Liquid Metal Catalysis with Ternary Alloys, Enhancing Activity in Propane Dehydrogenation ACS Catal. (IF 12.9) Pub Date : 2024-04-11 Michael Moritz, Sven Maisel, Narayanan Raman, Haiko Wittkämper, Christoph Wichmann, Mathias Grabau, Deniz Kahraman, Julien Steffen, Nicola Taccardi, Andreas Görling, Marco Haumann, Peter Wasserscheid, Hans-Peter Steinrück, Christian Papp
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Rhodium(II)-Catalyzed Asymmetric Cyclopropanation and Desymmetrization of [2.2]Paracyclophanes ACS Catal. (IF 12.9) Pub Date : 2024-04-11 Duc Ly, John Bacsa, Huw M. L. Davies
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Synthesis of Alkynylsilanes: A Review of the State of the Art Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-12 Krzysztof Kuciński
This contribution offers a comprehensive overview of methods for forging sp C–Si bonds. Over time, alkynylsilanes (silylacetylenes), once considered mere byproducts of hydrosilylation processes, have become essential building blocks in organic synthesis. This literature review traces the evolution of their synthesis, from traditional methodologies relying on organolithium and organomagnesium compounds
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Enantioselective Si‐H Insertion of Arylvinyldiazoesters Promoted by Rhodium(I)/Diene Complexes Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-12 Ziyan Li, Jian-Guo Liu, Wen-Ping Zhang, Ming-Hua Xu
An enantioselective Si‐H insertion between α‐arylvinyldiazoesters and silanes has been developed by employing rhodium(I)/chiral diene complex as the catalyst. This protocol offers a catalytic asymmetric approach to various chiral silanes containing α‐arylvinyl functionality at room temperature with good enantiocontrol (89‐99% ee). Transformation of the resulting enantiomerically enriched α‐arylvinyl‐α‐silyl
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Enzymatic Stereodivergent Access to Fluorinated β-Lactam Pharmacophores via Triple-Parameter Engineered Ketoreductases ACS Catal. (IF 12.9) Pub Date : 2024-04-11 Ze-Long Mei, Cong-Cong Li, Xu Han, Yu-Chen Tian, Shuo-Han Li, Weidong Liu, Ge Qu, Manfred T. Reetz, Zhoutong Sun, Jun-An Ma, Fa-Guang Zhang
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New and Revised Aspects of the Electrochemical Synthesis of Hydrogen Peroxide: From Model Electrocatalytic Systems to Scalable Materials ACS Catal. (IF 12.9) Pub Date : 2024-04-11 Marco Mazzucato, Alessandro Facchin, Mattia Parnigotto, Christian Durante
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CN22– Vacancies Enhance Ammonia Synthesis over Air-Durable Alkaline Earth Metal Cyanamide-Supported Cobalt Catalysts ACS Catal. (IF 12.9) Pub Date : 2024-04-10 Yihao Jiang, Masayoshi Miyazaki, Kazuki Miyashita, Masato Sasase, Kazuhisa Kishida, Hideo Hosono, Masaaki Kitano
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Interfacial Chemical-Bonded MoS2/In–Bi2MoO6 Heterostructure for Enhanced Photocatalytic Nitrogen-to-Ammonia Conversion ACS Catal. (IF 12.9) Pub Date : 2024-04-10 Taoxia Ma, Ruqi Li, Yu-Cheng Huang, Yuxuan Lu, Li Guo, Maomao Niu, Xin Huang, Razium Ali Soomro, Jingyu Ren, Qi Wang, Bin Xu, Chunming Yang, Feng Fu, Danjun Wang
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Z-Scheme Heterojunction α-Fe2O3/Tubular g-C3N4 with C Defects for Photocatalytic Degradation of Microcystin-LR in Water: Generation and Effect of Critical Species 1O2 ACS Catal. (IF 12.9) Pub Date : 2024-04-10 Haoxiang Zhong, Xiaodong Ji, Cheng Yang, Chunfang Tang, Xi Hu, Jingju Cai, Qiang Yin, Jiajia Wang, Xinjiang Hu, Xiaofei Tan, Mingshan Zhu
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Precision Synthesis of Sub-3 nm Bimetallic Alloy Nanoparticles for Efficient and Selective Catalytic Hydrogenolysis of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran ACS Catal. (IF 12.9) Pub Date : 2024-04-10 Zhibin Wen, Shumeng Zhang, Hao Yuan, Zhixue Zhang, Junlin She, Zhun Qiao, Zhaojun Liu, Kai Liu, Zhun Hu, Chuanbo Gao
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CO and O2 Interaction with Kinked Pt Surfaces ACS Catal. (IF 12.9) Pub Date : 2024-04-10 Fernando García-Martínez, Elia Turco, Frederik Schiller, J. Enrique Ortega
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A Microkinetic Model for Isomerizing Ethenolysis ACS Catal. (IF 12.9) Pub Date : 2024-04-10 Ziqiu Chen, Aaron D. Sadow, Baron Peters
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Mechanistic Insights into the Abrupt Change of Electrolyte in CO2 Electroreduction ACS Catal. (IF 12.9) Pub Date : 2024-04-10 Zhe Zheng, Yafei Yao, Wen Yan, Hangyu Bu, Jianfeng Huang, Ming Ma
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Complexes of Borane and 1,3,5‐Triazinane‐Derived Carbenes Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-11 Vladimir Smirnov, Vitalij Levin, Alexander D. Dilman
Complexes of borane with six‐membered N‐heterocyclic carbenes derived from readily accessible 1,3,5‐triazinium salts are described. Similar to the widely used imidazolium‐type borane complex, the obtained complexes behave as agents for the hydrogen atom transfer in the Giese reaction and as sources of the boryl radicals in addition to imines. The amine nitrogen of these complexes does not undergo alkylation
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Palladium‐Catalyzed/Mn(OAc)3‐Mediated 1,2‐Diazidation and 1,2‐Acetoxy/Hydroxylation of N‐Allyl Sulfonamides Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-11 Camilla Loro, Marta Papis, Sara Colombo, Leonardo Lo Presti, Giovanni Poli, Gianluigi Broggini, Julie Oble
Palladium‐catalyzed conditions for diazidation or acetoxy/hydroxylation of N‐allyl sulfonamides by using Pd(OAc)2 as the catalyst combined with Mn(OAc)3·2H2O have been developed. The 1,2‐diazidation reaction of the carbon‐carbon double bond occurs in mild conditions (i.e. NaN3 as azide source in THF at room temperature), whereas the 1,2‐acetoxy/hydroxylation requires an excess of Mn(OAc)3·2H2O. The
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Vacancy-Driven Ammonia Electrooxidation Reaction on the Nanosized CeOx Electrode in Nonaqueous Electrolyte ACS Catal. (IF 12.9) Pub Date : 2024-04-10 Xue Yang, Lu Sun, Xingyu Liu, Zekai Yang, Han Sun, Weiwei Liu, Haijun Chen
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Ultrahigh Throughput Evolution of Tryptophan Synthase in Droplets via an Aptamer Sensor ACS Catal. (IF 12.9) Pub Date : 2024-04-10 Remkes A. Scheele, Yanik Weber, Friederike E. H. Nintzel, Michael Herger, Tomasz S. Kaminski, Florian Hollfelder
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Synthesis of 1-(Halo)alkyl-3-heteroaryl Bicyclo[1.1.1]pentanes Enabled by a Photocatalytic Minisci-type Multicomponent Reaction ACS Catal. (IF 12.9) Pub Date : 2024-04-10 Jiashun Zhu, Yu Hong, Yuxin Wang, Yirui Guo, Yuru Zhang, Zhigang Ni, Wanmei Li, Jun Xu
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PhotoROMP: The Future Is Bright ACS Catal. (IF 12.9) Pub Date : 2024-04-10 Andrew J. Greenlee, Raymond A. Weitekamp, Jeffrey C. Foster, Samuel C. Leguizamon
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Enantioselective Reductive Conjugate Alkenylation of α,β-Unsaturated Ketones and Amides via Nickel Catalysis ACS Catal. (IF 12.9) Pub Date : 2024-04-10 Mengxin Zhao, Luoqiang Zhang, Jianrong Steve Zhou
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Solid‐phase Synthesis of Peptidols via Reductive Cleavage through a Benzotriazole Linker Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-10 Szu-Hsuan Chen, Hui-Ying Chuang, Chitra Rajavel, Yi Kai Lin, Shu-Han Chang, Pei-Chen Tsai, Hui-Ting Chen, Chung-Ming SUN, Anand Selvaraj, Chai-Lin kao
Peptidols were prepared through the reductive cleavage of benzotriazole intermediates obtained from the on‐bead activation of 3,4‐diaminobenzoyl linkers. Remarkably, this method used commercially available amino acid residues and resins without further modification. Pure peptidols were collected with only filtration in 49%–87% yield. Only the derivatives with aspartic acid as the first C‐terminal residue
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TBHP‐Mediated Hydroxyperfluoroalkylation of Alkenes with Perfluoroalkyl Iodides to Construct β‐Perfluoroalkyl Alcohols Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-10 Jiantao Zhang, Weiming Zhu, Renhua Su, Duoduo Xiao, Peng Zhou, Kai Chen, Min Zhang, cui chen, Weibing Liu
A three‐component strategy for the synthesis of β‐perfluoroalkyl allyl alcohols from 1,3‐dienes is developed. A diverse range of synthetically valuable β‐perfluoroalkyl allyl alcohols are obtained in moderate to high yields. Broad substrate scope and good functional group tolerance are observed. This method is also applicable to mono‐olefins and 1,3‐enynes. The control experiment results demonstrate
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n‐Bu4NI/K2S2O8 Mediated Csp2‐Csp2 Bond Cleavage – Transformylation from p‐Anisaldehyde to Primary Amides Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-10 Xiaochen Liu, Samual Hee, Netanel Sapir, Alvin Li, Jianbo Liu, Yu Chen
n‐Bu4NI/K2S2O8 mediated transformylation from p‐anisaldehyde to primary amides is reported. The mechanistic studies suggest the reaction occurs via a single electron transfer pathway. Based on the DFT electronic structure calculations of various reaction pathways, the most plausible mechanism involves the formation of a phenyl radical cation and an arenium ion as the key intermediates. It represents