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Identification of Commercial Stainless‐Steel Mesh Size for Electrochemical Oxygen Evolution Reaction Chem. Asian J. (IF 4.1) Pub Date : 2024-04-16 Yuda Prima Hardiantoa, Mostafa M. Mohamed, Md. Abdul Aziz, , Zain H. Yamani
The study examines the oxygen evolution reaction (OER) electrocatalytic efficiency of various stainless‐steel mesh (SSM) sizes in electrolytic cells. Stainless steel is chosen due to its widespread availability and stability, making it an economically viable option. The primary objective of this investigation is to determine the optimal stainless‐steel mesh size among those currently widely available
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A Concise Route to Keto‐Bridged Polyphenols by Photo‐Fries Rearrangement in Flow Chem. Asian J. (IF 4.1) Pub Date : 2024-04-15 Xin-Jie Lin, Chien-Lung Wang, Chi-How Peng, Hsueh-Ju Liu, Yen-Ku Wu
Described is a new synthetic route to bis(2‐hydroxy‐3,5‐di‐t‐butylphenyl)methanone and its derivatives. The combined esterification/photo‐Fries rearrangement approach enables a modular preparation of keto‐bridged polyphenols. This protecting group‐free process is highly atom‐ and step‐economic, and a scalable production was easily achieved in the continuous‐flow mode.
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New Pyridine Dicarbene Ligands with Ring Expanded NHCs and their Nickel and Chromium Complexes Chem. Asian J. (IF 4.1) Pub Date : 2024-04-15 Evangelos Papangelis, Katrin Pelzer, Christophe Gourlaouen, Dominique Armspach, Pierre Braunstein, Andreas A. Danopoulos, Corinne Bailly, Nikolaos Tsoureas, Dimitrios Triantafyllos Gerokonstantis
The pincer complexes [NiIIBr(CNC)]Br (4), [CrIIIBr3(CNC)] (5a) and [CrIIIBr2.3Cl0.7(CNC)] (5b), where CNC = 3,3'‐(pyridine‐2,6‐diyl)bis(1‐mesityl‐3,4,5,6‐tetrahydropyrimidin‐2‐ylidene), were obtained from the novel ligand CNC, generated in situ from the precursor (CHNCH)Br2 and [NiIIBr2(PPh3)2] or from [CrII{N(SiMe3)2}2(THF)2] and (CHNCH)Br2 by aminolysis, respectively. The tetrahedrally distorted
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Homogeneous and Heterogeneous Frustrated Lewis Pairs for the Activation and Transformation of CO2 Chem. Asian J. (IF 4.1) Pub Date : 2024-04-12 Tao Du, Peng Zhang, Zhen Jiao, Jiancheng Zhou, DING YUXIAO
Due to the serious ecological problems caused by the high CO2 content in the atmosphere, reducing atmospheric CO2 has attracted widespread attention from academia and governments. Among the many ways to mitigate CO2 concentration, the capture and comprehensive utilization of CO2 through chemical methods have obvious advantages, whose key is to develop suitable adsorbents and catalysts. Frustrated Lewis
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Na/N Co‐doped Seaweed Biochar Composite for Efficient Removal of Aqueous Pb(II) and Cu(II) Chem. Asian J. (IF 4.1) Pub Date : 2024-04-12 Meiyuan Fu, Qianhui Ma, Yun Luo, Wen Feng, Xianghui Wang
Pollution from harmful heavy metal ions such as Pb(II) and Cu(II) is causing serious environmental and health problems. In this study, Sodium and nitrogen co‐doped porous carbon material (Na/NABc) was successfully prepared from seaweed, sodium hydroxide, and dicyandiamide. The experimental results showed that Na/NABc is an excellent adsorbent for the effective removal of Pb(II) and Cu(II) from water
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Tuning Green Explosives through SNAr Chemistry Chem. Asian J. (IF 4.1) Pub Date : 2024-04-11 Sergei Nikitin, Frederik Diness
Reactivity and regioselectivity of SNAr‐type fluorine substitution with azide in polyfluoronitrobenzenes was studied both theoretically and experimentally. The obtained polyazidonitrobenzene derivatives were extensively characterized by NMR, IR, HPLC, X‐ray, and DFT methods. It was found that the substitution with the azide nucleophile occurs first at the para‐ and the ortho‐positions to the NO2‐group
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Biomaterials for Targeting Endoplasmic Reticulum in Cancer Chem. Asian J. (IF 4.1) Pub Date : 2024-04-11 Tripti Mishra, Poulomi Sengupta, Sudipta Basu
Endoplasmic reticulum (ER) is one of the most important sub‐cellular organelles which controls myriads of biological functions including protein biosynthesis with proper functional folded form, protein misfolding, protein transport into Golgi body for secretion, Ca2+ homeostasis and so on. Subsequently, dysregulation in ER function leads to ER stress followed by disease pathology like cancer. Hence
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Pincer Nickel‐Catalyzed Olefination of Alcohols with Benzylphosphine Oxides Chem. Asian J. (IF 4.1) Pub Date : 2024-04-11 Yu-Tong Duan, Bo Yang, Zhong-Xia Wang
N,N,P‐Pincer nickel complexes effectively catalyze reaction of alcohols with benzylphosphine oxides to form alkenes in good yields. The protocol suits for a wide scope of substrates and generates only E‐configurated alkenes. The method also shows good compatibility of functional groups. Methoxy, methylthio, trifluoromethyl, ketal, fluoro, chloro, bromo, thienyl, and furyl groups are tolerated. The
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Organocatalyzed Hydroacylation of Enones by Photosensitization of Acyl Silanes Chem. Asian J. (IF 4.1) Pub Date : 2024-04-11 Shiv Shankar Patel, Samiksha Gupta, CHANDRA BHUSHAN TRIPATHI
A mild protocol for hydroacylation of enones through photosensitization of acyl silanes with thioxanthone under blue light (455 nm) irradiation is reported. A Brønsted acid is used as a co‐catalyst in the reaction. The versatility of the method is demonstrated through inter‐ and intramolecular hydroacylation reaction. The hydroacylation product is applied for synthesizing an anti‐HCV agent. Mechanistic
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Ambient Temperature Metal‐Free Thiomethylation of Chloroheteroarenes and Chloropurines Chem. Asian J. (IF 4.1) Pub Date : 2024-04-10 Manisha Patel, Ra K Vora, Yogesh S Sanghvi, anant kapdi
Herein, we report an in‐situ mild and metal‐free protocol for thiomethylation of heteroarenes in high yields. The thiomethylation of various chloropurines, nucleosides, and chloroheteroarenes has been accomplished offering easy access to agrochemicals and synthetic molecules useful for drug discovery.
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Sustainable harnessing of waste polycarbonate for synthesizing activated furans to generate Stenhouse adducts on polymer surface Chem. Asian J. (IF 4.1) Pub Date : 2024-04-10 Lisa Zeußel, Shefali Chowdhary, Wu Haocheng, Vipan Kumar, Sukhdeep Singh
Plastics are versatile materials, offering lightweight, durable, and affordable solutions across various industries. However, their non‐degradable nature poses challenges by end of their life. This study presented an innovative carbonyl extraction method to utilize waste poly(bisphenol A carbonate) (PC) as reaction precursor to synthesis of activated furan as precursor for photoswitchable Stenhouse
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Phosphine‐Mediated Dimerization of Open‐[60]Fullerenes Chem. Asian J. (IF 4.1) Pub Date : 2024-04-09 Shu Okamoto, Yoshifumi Hashikawa, Yasujiro Murata
By a reaction of trimethylphosphine with an open‐[60]fullerene, corresponding dimers could be generated via two‐fold deoxygenation processes even though the formation of β‐oxo‐phosphorous ylide is inevitable, a part of which is hydrolyzed to yield an α‐methylene carbonyl derivative. Nevertheless, Wittig reaction and aldol condensation did not proceed well, indicating the presence of an unknown dimerization
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Progress in electrochemically empowered C‐O bond formation: Unveiling the pathway of efficient green synthesis Chem. Asian J. (IF 4.1) Pub Date : 2024-04-08 Debosmit Ghosh, Aroop Kumar Samal, Anita Parida, Mohammed Ikbal, Akash Jana, Rathin Jana, Pradeepta Kumar Sahu, Soumen Giri, Shubhankar Samanta
(C‐X) bonds (X= C, N, O) are the main backbone for making different skeleton in the organic synthetic transformations. Among all the sustainable techniques, electro‐organic synthesis for C‐X bond formation is the advanced tool as it offers a greener and more cost‐effective approach to chemical reactions by utilizing electrons as reagents. In this review, we want to explore the recent advancements in
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Magnesium Magic: State‐of‐the‐Art Nanocrystalline Materials Paving the Way for Hydrogen Storage Chem. Asian J. (IF 4.1) Pub Date : 2024-04-06 guanglei tan, Dan Tang, Lijie He, Lili Guo, Mohamed Bououdina, Mohsin Ali Marwat, Quanqing Zhang, Muhammad Humayun
Hydrogen has been regarded as a promising alternative to traditional fossil fuels, presenting itself as a viable and environmentally friendly energy choice. The design and fabrication of highly efficient hydrogen storage materials is crucial to the wide utilization of hydrogen‐based technologies. Magnesium‐based nanocrystalline materials have received significant interest in the field of hydrogen storage
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Palladium‐Catalyzed C3‐Carbaldehyde Directed Regioselective C2‐Thioarylation of Indoles Chem. Asian J. (IF 4.1) Pub Date : 2024-04-05 Sandip Kumar Gupta, Niranjan Panda
Palladium‐catalyzed thioarylation of indoles by diaryl disulfides in the presence of phenyliododiacetate is reported. The directing potential of weakly coordinating aldehyde group present at 3‐position of indole was exploited for regioselective C2‐H thioarylation over the possible C4‐H functionalization. Mechanistic studies reveal that the process involves initial generation of thioaryl radical followed
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Recent advances in photosensitizer materials for light‐mediated tumor therapy Chem. Asian J. (IF 4.1) Pub Date : 2024-04-05 Minle Chen, Qianru Zhu, Zhenzhen Zhang, Qiushui Chen, Huanghao Yang
Photodynamic therapy (PDT) as an emerging therapeutic method has drawn many attentions in the treatment field for cancer. Photosensitizer, which can convert photon energy into cytotoxic species under light irradiation, is the core component in PDT. The design of photosensitizers still faces problems of light absorption, targeting, penetration and oxygen dependence. With the rapid progress of material
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An Air‐Stable Storage Compound for White Phosphorus: Reversible Addition to a Stannylene and Chemical Release of P4 Chem. Asian J. (IF 4.1) Pub Date : 2024-04-05 Beate G. Steller, Clara A. Roller, Michaela Flock, Roland C. Fischer
Controlled insertion into a single P‐P bond of white phosphorus (P4) was achieved by employing a diaryl stabilized stannylene, Ar*2Sn (Ar* = 2,6‐bis(benzhydryl)‐4‐iPr‐phenyl). Conversions of the stannylene with P4 gave a non‐pyrophoric, air‐stable storage compound, which releases P4 quantitively upon irradiation with light (354 or 455 nm). Alternatively, the phosphorus cage is detached by reacting
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Recent Advances on Diarylethene‐Based Photoswitching Materials: Applications in Bioimaging, Controlled Singlet Oxygen Generation for Photodynamic Therapy and Catalysis Chem. Asian J. (IF 4.1) Pub Date : 2024-04-05 Sayan Kumar Bag, Adwitiya Pal, Subhendu Jana, Arunabha Thakur
Diarylethenes (DAE), a class of best performing photoswitchable compounds, where the key features of stability, photoisomerization wavelengths, quantum yield and variability in the photoisomers significantly depend on their derivatization. The last decade has witnessed a surge in the engagement of DAEs to different areas of chemical and biological impacts like catalysis in synthetic organic chemistry
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Fluoro and Trifluoromethyl Benzoyl Hypoiodite Complexes with Substituted Pyridines Chem. Asian J. (IF 4.1) Pub Date : 2024-04-05 Václav Kolařík, Kari Rissanen, Jas S. Ward
Based on the prior observation of the trifluoroacetate hypoiodite, CF3C(O)OI, demonstrating the largest σ‐hole of a neutral halogen bond donor, a series of mono‐ and bis‐carbonyl hypoiodites utilising trifluoromethyl or fluorine substituents at various positions of a parent benzoyl skeleton have been synthesised. The carbonyl hypoiodite complexes were prepared via cation exchange of the silver(I) cations
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Metal‐Free Visible‐Light Catalytic Deoxygenation of Azaaryl N‐Oxides: Harnessing Photons for Efficient Greener Synthesis Chem. Asian J. (IF 4.1) Pub Date : 2024-04-05 Susanta Mandal, Kimron Protim Phukan, Joneswar Basumatary, Biswajit Gopal Roy
Regio‐ and chemo‐selective functionalization of electron deficient azaarenes often required their transformations to corresponding N‐oxides and subsequent removal of oxygen after functionalization to get back the desired substituted azaarenes. An efficient metal‐free visible‐light photo‐redox catalytic deoxygenation of N‐oxides of azaheterocyclic compounds has been developed using acridinium based
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One‐Pot Assembly of 2‐Trifluoromethyl Benzothiazole and Benzoselenazole via Copper‐Mediated Three‐Component Cascade Reaction Chem. Asian J. (IF 4.1) Pub Date : 2024-04-05 Yangjie Huang, Chenhui You, Biqiong Hong, Xiaoyan Han, Zhiqiang Weng
A domino one‐pot synthesis of 2‐(trifluoromethyl)benzothiazole via copper‐mediated three‐component cascade reaction starting from the easily accessible starting materials such as o‐iodoanilines, methyl trifluoropyruvate, and elemental sulfur is reported. The present strategy displayed a comprehensive substrate scope and good functional group tolerance and enabled access to a variety of substituted
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Efficient absorption of CO2 by protic‐ionic‐liquid based deep eutectic solvents Chem. Asian J. (IF 4.1) Pub Date : 2024-04-03 Shuyue Wen, Xiaomin Zhang, Youting Wu
Carbon capture, utilization, and storage (CCUS) are among the key technologies to achieve large‐scale carbon emission reduction globally. Deep eutectic solvents (DESs) are considered as designable solvents, which has attracted intensive attention for CO2 capture. Here, a series of binary DESs are synthesized through one‐step mixing with the starting materials of protic ionic liquid (PIL) and amine
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Luminogenic and Bactericidal Studies of an Acrylonitrile‐based AIEgen Chem. Asian J. (IF 4.1) Pub Date : 2024-04-03 Sagnik De, Debolina Ghosh, Gopal Das
We have synthesized an aggregation induced emissive molecule that exhibits promising photophysical characteristics. The aggregating aptitude is demonstrated by binary solvent mixture and it is emissive in both solution and solid state. The luminogenic characteristics are employed in creating fluorescent inks as well as for the detection of nitro antibiotics in biofluids and in solid support. Moreover
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Development of Anisotropic Electrically Conductive GNP-reinforced PCL-Collagen Scaffold for Enhanced Neurogenic Differentiation under Electrical Stimulation Chem. Asian J. (IF 4.1) Pub Date : 2024-03-28 Souvik Ghosh, Partha Roy, Debrupa Lahiri
The internal electric field of the human body plays a crucial role in regulating various biological processes, such as, cellular interactions, embryonic development and the healing process. Electrical stimulation (ES) modulates cytoskeleton and calcium ion activities to restore nervous system functioning. When exposed to electrical fields, stem cells respond similarly to neurons, muscle cells, blood
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A Porphyrin‐Based 3D Metal−Organic Framework Featuring [Cu8Cl6]10+ Cluster Secondary Building Units: Synthesis, Structure Elucidation, Anion Exchange, and Peroxidase‐like Activity Chem. Asian J. (IF 4.1) Pub Date : 2024-04-02 Chun-Mei Zeng, Song-Yu Luo, Xiao Wang, Feng-Lin Cao, Ze-Sheng Zhang, Wen-Hua Zhang, Chun-Lei Dai, David J. Young
Herein, we report a rare example of cationic three‐dimensional (3D) metal−organic framework (MOF) of [Cu5Cl3(TMPP)]Cl5•xSol (denoted as Cu‐TMPP; H2TMPP = meso‐tetrakis (6‐methylpyridin‐3‐yl) porphyrin; xSol = encapsulated solvates) supported by [Cu8Cl6]10+ cluster secondary building units (SBUs) wherein the eight faces of the Cl−‐based octahedron are capped by eight Cu2+. Surface‐area analysis indicated
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HA‐Based pH‐Responsive Calcium Ions and Crocetin Releasing Hydrogel for Accelerating Skin Wound Healing Chem. Asian J. (IF 4.1) Pub Date : 2024-04-01 Li Wang, Xuemei Ma, Yanan Pan, Haoxiang Ye, Zike Liu, Zaoyuan Kuang, Zhongxiang Zhao, Aijun Liu, Yuxing Ji
The ideal and highly anticipated dressing for skin wounds should provide a moist environment, possess antibacterial properties, and ensure sustained drug release. In the present work, a pH‐responsive hyaluronic acid‐based hydrogel (CPC@HA hydrogel) was formed by hydrogen bond and amido bond cross‐linking after introducing crocetin (Cro) and CaCO3@polyelectrolyte microspheres (CaCO3@PEM) to HA hydrogel
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Microflow, Sequential Coupling and Cyclization Approach for Synthesis of Cyclic Phosphotriesters from PCl3 Chem. Asian J. (IF 4.1) Pub Date : 2024-04-01 Kohei Nakabayashi, Hiroshi Kitamura, Shinichiro Fuse
An approach for the synthesis of cyclic phosphotriesters with various ring sizes (5‐ to 8‐membered rings) from phosphorus trichloride and diols was developed. The major challenge in developing this approach is the suppression of the undesired reactions caused by substrates containing multiple highly reactive sites. These undesired reactions were successfully suppressed by microflow technology, which
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Robust Graphene‐based Aerogel for Integrated 3D Asymmetric Supercapacitors with High Energy Density Chem. Asian J. (IF 4.1) Pub Date : 2024-03-29 Xue Liang, Lijun Tang, Yongchao Zhang, Xiaodong Zhu, Jian Gao
Three‐dimensional asymmetric supercapacitors (3D ASC) have garnered significant attention due to their high operating window, theoretical energy density, and circularity. However, the practical application of 3D electrode materials is limited by brittleness and excessive dead volume. Therefore, we propose a controlled contraction strategy that regulates the pore structure of 3D electrode materials
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Biocompatible Gold Nanoparticles‐Modified Fluorine Doped Tin Oxide Electrode for the Fabrication of Enzyme‐Free Glucose Sensor Chem. Asian J. (IF 4.1) Pub Date : 2024-03-28 S. M. Abu Nayem, Santa Islam, Syed Shaheen Shah, Abdul Awal, William Ghann, Deepak Anand, Irshad Ahmad, Jamal Uddin, Md. Abdul Aziz, A. J. Saleh Ahammad
This work demonstrates the use of jute stick extract as a reducing and stabilizing agent for the synthesis of spherical gold nanoparticles (AuNPs). In UV‐Vis spectroscopy, peak at 550 nm was used to confirm the formation of AuNPs. The spherical surface morphology of AuNPs was determined through SEM and TEM analysis. While XRD investigation revealed the crystallinity of the prepared AuNPs. To ensure
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MXene/silk fibroin strengthened PVA‐based eutectogel with excellent self‐healing ability and environmental adaptability: Design, synthesis, and sensing application Chem. Asian J. (IF 4.1) Pub Date : 2024-03-28 Hanlin Zhai, Chen Yue, Zhangpeng Li, Limin Ma, Tingting Wang, Hong Zhang, Jinqing Wang, Shengrong Yang
In order to solve typical problems of instability in a variety of environments, lack of self‐healing ability and poor mechanical properties of traditional hydrogel materials, herein, a superelastic self‐healing eutectogel of DPMS was designed and prepared in a deep eutectic solvent (DES) system using poly(vinyl alcohol) (PVA) as the bulk skeleton material, while two‐dimensional MXene (Ti3C2TX) nanosheets
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Ultrasonic‐Assisted Nitrate Anion Incorporation in Triaminoguanidium Chloride Based Covalent Organic Polymer For Methylene Blue Dye Adsorption Chem. Asian J. (IF 4.1) Pub Date : 2024-03-27 Naranarayan Deori, Saurav Paul, Surabhi Lahkar, Sanfaori Brahma
. Terephthalaldehyde‐triaminoguanidium chloride covalent organic polymer, Te‐TGCl COP can facilely be incorporated with NaNO3 by sonication. Te‐TGCl COP incorporated with NaNO3 via ultrasonication adsorbs Methylene Blue (MB) dye. Te‐TGCl COP alone shows negligible adsorption capacity for MB, however, when treated with NaNO3, its adsorption capacity emerges slightly. However, Te‐TGCl‐NaNO3 COP composite
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Aggregation‐Induced Emission of Naphthalene Diimides: Effect of Chain Length on Liquid and Solid‐Phase Emissive Properties Chem. Asian J. (IF 4.1) Pub Date : 2024-03-26 Alberto Insuasty, Serena Carrara, Xuechen Jiao, Christopher R. McNeill, Conor Hogan, Steven J Langford
The aggregation‐induced emission (AIE) properties of a systematic series of naphthalene diimides (NDIs) varying the chain length at the imide positions have been studied. A solvophobic collapse of NDI units through the flash injection of THF NDI solutions in sonicating water triggers the formation of stable suspensions with enhanced fluorescence emissions. Shorter chains favor the π−π stacking of NDI
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CO2‐Free Ethylene Oxide Production via Liquid‐Phase Epoxidation with Fe2O3/MSM Catalyst Chem. Asian J. (IF 4.1) Pub Date : 2024-03-25 Muhammad Maqbool, Nazia Parveen, Saima Jaffar, Sadaf Ul Hassan, Asif Mahmood, Waheed Al-Masry, Shumaila Razzaque, Toheed Akhter, Taewook Kim, Soo-Kyung Han, Chan Ho Park
In this study, we present an approach for ethylene oxide (EO) production that addresses environmental concerns by eliminating greenhouse gas emissions. Our catalyst, Fe2O3/MSM, was synthesized using a hydrothermal method, incorporating Fe2O3 nanoparticles into a well‐structured mesoporous silica matrix (MSM). We selected peracetic acid as the oxidant, enabling CO2‐free EO production while yielding
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Quinone methide based self‐immobilizing molecular fluorescent probes for in situ imaging of enzymes Chem. Asian J. (IF 4.1) Pub Date : 2024-03-22 Yeru Miao, Zhen-Qing Yu, Shuai Xu, Mei Yan
Enzymes play important roles not only in normal physiological processes but in the development of many diseases. In situ imaging of enzymes with high‐resolution in living systems would helpful for clinical diagnosis and treatment. However, many molecular fluorescent probes suffer from the drawback of diffusing away from the reaction site of enzymes even out of the cells, losing the in situ information
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Light Responsive DNA Nanomaterials and Their Biomedical Applications Chem. Asian J. (IF 4.1) Pub Date : 2024-03-21 Raja Muhammad Aqib, Arsalan Umer, Jialin Li, Jianbing Liu, Baoquan Ding
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Ligand‐free MnBr2‐Catalyzed Chemo‐ and Stereoselective Hydroboration of Terminal Alkynes Chem. Asian J. (IF 4.1) Pub Date : 2024-03-21 Rameshwar B. Pawar, Mital H. Karmur, Benudhar Punji
Developing simple and benign protocols for synthesizing alkenylboronates is crucial as they are synthetically valuable compounds in various organic transformations. In this work, we report a straightforward ligand‐free protocol for synthesizing alkenylboronates via atom‐economical hydroboration of alkynes with HBpin catalyzed by a manganese salt. The reaction shows a high level of chemo and regioselectivity
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Sustainable Vat Photopolymerization-Based 3D-Printing through Dynamic Covalent Network Photopolymers Chem. Asian J. (IF 4.1) Pub Date : 2024-03-20 Sirawit Pruksawan, Yi Ting Chong, Wylma Zen, Terence Jun En Loh, FuKe Wang
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The (o‐p‐o)‐Terphenyl Embedded Calix[2]phyrin(2.2. 1 .1. 1 ) and Its Cu(II) Complex Chem. Asian J. (IF 4.1) Pub Date : 2024-03-20 Sourav Ranjan Pradhan, Chetan Kumar Prasad, Mainak Das, Alagar Srinivasan
The introduction of a higher arene unit as a structural motif is unprecedented in calixphyrin chemistry. Herein, the syntheses, spectral and structural characterization of heretofore anonymous terphenylene unit (o‐p‐o) incorporated calixphyrin with fused sp2meso carbons is reported. The explicitly tailored macrocyclic core is utilized to stabilize the Cu(II) metal ion. The molecular structures of the
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Structural Insights on the Role of Halogen Bonding in Protein MEK Kinase-Inhibitor Complexes Chem. Asian J. (IF 4.1) Pub Date : 2024-03-19 Pietro Milesi, Francesca Baldelli Bombelli, Luisa Lanfrancone, Rosa M. Gomila, Antonio Frontera, Pierangelo Metrangolo, Giancarlo Terraneo
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Metal‐Organic Frameworks‐Derived Nanocarbon Materials and Nanometal Oxides for Photocatalytic Applications Chem. Asian J. (IF 4.1) Pub Date : 2024-03-19 Jun-Qing Ye, Shu-Ying Xu, Qian Liang, Yan-Zi Dai, Ming-Yang He
Harnessing low‐density solar energy and converting it into high‐density chemical energy through photocatalysis has emerged as a promising avenue for the production of chemicals and remediation of environmental pollution, which contributes to alleviating the overreliance on fossil fuels. In recent years, metal‐organic frameworks (MOFs) have gained widespread application in the field of photocatalysis
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Front Cover: Design, Synthesis, and Characterization of Novel Styryl Dyes as Fluorescent Probes for Tau Aggregate Detection in Vitro and in Cells (Chem. Asian J. 6/2024) Chem. Asian J. (IF 4.1) Pub Date : 2024-03-18 Withsakorn Sangsuwan, Kriangsak Faikhruea, Kotchakorn Supabowornsathit, Don Sangsopon, Praewphan Ingrungruanglert, Hathaichanok Chuntakaruk, Napatsaporn Nuntavanotayan, Kittiporn Nakprasit, Nipan Israsena, Thanyada Rungrotmongkol, Pitak Chuawong, Tirayut Vilaivan, Chanat Aonbangkhen
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Synthesis of R‐GABA Derivatives via Pd(II) Catalyzed Enantioselective C(sp3)‐H Arylation and Virtual Validation with GABAB1 Receptor for Potential leads Chem. Asian J. (IF 4.1) Pub Date : 2024-03-18 Smitha Mohanlal, Diprupa Saha, Shubhant Pandey, Rudresh Acharya, Nagendra K Sharma
GABA (γ‐amino butyric acid) analogues like baclofen, tolibut, phenibut, etc., are well‐known GABAB1 inhibitors and pharmaceutically important drugs. However, there is a huge demand for more chiral GABA aryl analogues with promising pharmacological actions. Here, we demonstrate the chiral ligand acetyl‐protected amino quinoline (APAQ) mediated enantioselective synthesis of GABAB1 inhibitor drug scaffolds
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Nucleophilic Selenocyclization Reaction of Benzodiynes Promoted by Sodium Selenide: Synthesis of Isoselenochromenes Chem. Asian J. (IF 4.1) Pub Date : 2024-03-18 Adriano Maroneze, Fabíola Caldeira, Davi Back, Cristina Nogueira, Gilson Zeni
We describe here the synthesis of isoselenochromenes via a nucleophilic selenocyclization reaction of benzodiynes with sodium selenide. The central parameters that affect this cyclization reaction were studied, and the best reaction conditions were applied to different substrates to determine the scope of the method. The results indicated that isoselenochromenes were obtained in higher yields when
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Revisiting Stereoselective Propene Polymerization Mechanisms: Insights through the Activation Strain Model Chem. Asian J. (IF 4.1) Pub Date : 2024-03-17 Eugenio Romano, Vincenzo Barone, Peter H. M. Budzelaar, Claudio De Rosa, Giovanni Talarico
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Dual Functional Microcapsule based on Monodisperse Short PEG Amphiphile for Drug Encapsulation and Protein Affinity Controlled Release Chem. Asian J. (IF 4.1) Pub Date : 2024-03-15 Rohit N. Ketkar, Paritosh Dey, Triveni Sodnawar, Shilpy Sharma, Manikandan M, Sharmistha Dutta Choudhury, Nabanita Sadhukhan
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Electro-oxidative Methylation of 2-Isocyanobiaryls Using N,N-dimethylformamide (DMF) as Carbon Source: Synthesis of 6-Methylphenanthridines Chem. Asian J. (IF 4.1) Pub Date : 2024-03-15 Kannika La-ongthong, Teera Chantarojsiri, Darunee Soorukram, Pawaret Leowanawat, Vichai Reutrakul, Chutima Kuhakarn
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Synthesis of Naphthalimide Azocarboxylates Showing Turn-On Fluorescence by Substitution Reaction with Sulfinates** Chem. Asian J. (IF 4.1) Pub Date : 2024-03-14 Hiroki Tanimoto, Shogo Kyogaku, Aoi Otsuki, Takenori Tomohiro
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Front Cover: Interfacial Activity of Janus Particle: Unity of Molecular Surfactant and Homogeneous Particle (Chem. Asian J. 5/2024) Chem. Asian J. (IF 4.1) Pub Date : 2024-03-14 Haipeng Liu, Yingchun Long, Fuxin Liang
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Facile Preparation of Impalement Resistant, Mechanically Robust and Weather Resistant Photothermal Superhydrophobic Coatings for Anti-/De-icing Chem. Asian J. (IF 4.1) Pub Date : 2024-03-13 Jinfei Wei, Weidong Liang, Mingyuan Mao, Bucheng Li, Junping Zhang
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Wet-Chemical Synthesis of Elemental 2D Materials Chem. Asian J. (IF 4.1) Pub Date : 2024-03-12 Yue Xu, Junlei Qi, Cong Ma, Qiyuan He
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Carbazole Based Smaragdyrins: Synthesis, Aromaticity Switching, and Formation of a Spiro-Dimer Chem. Asian J. (IF 4.1) Pub Date : 2024-03-08 Jinchao Chen, Haigen Nie, Yutao Rao, Ling Xu, Mingbo Zhou, Bangshao Yin, Jianxin Song, Atsuhiro Osuka
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0-D and 1-D Perovskite-like Hybrid Bismuth(III) Iodides Chem. Asian J. (IF 4.1) Pub Date : 2024-03-07 Aditi Saraswat, Pratap Vishnoi
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Frustrated Lewis Pair-Type Reactivity of Intermolecular Rare-Earth Aryloxide and N-Heterocyclic Carbene/Olefin Combinations Chem. Asian J. (IF 4.1) Pub Date : 2024-03-07 Yiwen Guan, Kejian Chang, Yujie Su, Xian Xu, Xin Xu
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Recent Advances of Chiral Small Organic Molecules: Structure and Properties for Circularly Polarized Luminescence Chem. Asian J. (IF 4.1) Pub Date : 2024-03-07 Tingwei Zhang, Yue Zhang, Zhiyuan He, Tingjun Yang, Xu Hu, Tengfei Zhu, Yuhai Tang, Yanfeng Zhang, Jiao Jiao
Circularly polarized luminescence (CPL) refers to the emission of light with distinguishable left or right circular polarization in non‐racemic systems. CPL has attracted significant attention due to its potential applications in future displays, photonics technologiesIn recent years, there has been significant development in the field of circularly polarized luminescent (CPL) materials based on small
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Recent Advances in NHC-Catalyzed Chemoselective Activation of Carbonyl Compounds Chem. Asian J. (IF 4.1) Pub Date : 2024-03-07 Yixian Huang, Xiaolin Peng, Tingting Li
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Hard Carbon Derived From Different Precursors for Sodium Storage Chem. Asian J. (IF 4.1) Pub Date : 2024-03-06 Wanli Wang, Bin Wang, Yuqi Li, Ning Wang, Yujie Xu, Chongze Wang, Yi Sun, Han Hu
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Recent Advances in Detection of Hydroxyl Radical by Responsive Fluorescence Nanoprobes Chem. Asian J. (IF 4.1) Pub Date : 2024-03-06 Mazen Alanazi, Jiaxi Yong, Miaomiao Wu, Zexi Zhang, Dihua Tian, Run Zhang
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Two Energetic Framework Materials Based on DNM–TNBI as Host Molecule: Effectively Coordinated by Different Cations Chem. Asian J. (IF 4.1) Pub Date : 2024-03-06 Boqian Yang, BiBo Li, Yang Liu, Chuanhao Xu, Shangbiao Feng, Shuhai Zhang
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Controllable Chemoselectivity Cascade Reactions for the Synthesis of Phenanthrenols via Palladium-Catalyzed-Suzuki/Heck Reaction and Michael Addition Chem. Asian J. (IF 4.1) Pub Date : 2024-03-05 Phornphan Yongpanich, Kamonlak Chatrangsan, Jumreang Tummatorn, Charnsak Thongsornkleeb, Somsak Ruchirawat