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Photochemical water splitting via transition metal complexes J. Catal. (IF 7.3) Pub Date : 2024-03-12 Antonio Rosales Martínez, Ignacio Rodríguez-García
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Defect modulation of MIL-68(Fe) MOFs by Cu doping for boosting photocatalytic N2 fixation J. Catal. (IF 7.3) Pub Date : 2024-03-11 Zewei Zhang, Cheng Liu, Yueling Chen, Qi Chen, Yingzhang Shi, Zhiwen Wang, Jinhong Bi, Jimmy C. Yu, Ling Wu
A series of Fe-based MOFs MIL-68(Fe) with different defect contents were prepared and modulated by doping different amounts of Cu ions for photocatalytic N fixation by converting N and HO into NH and O.
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Kinetics and reaction mechanism of Pd-Catalyzed chlorobenzene hydrogenolysis J. Catal. (IF 7.3) Pub Date : 2024-03-11 Nikki Kragt, Jalal Tavana, Mohammed Al-Gharrawi, M. Clayton Wheeler, David Hibbitts, Thomas J. Schwartz
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Water film-mediated photocatalytic oxidation of oxalate on TiO2 J. Catal. (IF 7.3) Pub Date : 2024-03-11 N. Tan Luong, Khalil Hanna, Jean-François Boily
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High-Pressure oxidative coupling of methane on alkali metal catalyst – Microkinetic analysis and operando thermal visualization J. Catal. (IF 7.3) Pub Date : 2024-03-11 Yuhang Yu, Keisuke Obata, William J. Movick, Shintaro Yoshida, Jose Palomo, Sean-Thomas B. Lundin, Atsushi Urakawa, S. Mani Sarathy, Kazuhiro Takanabe
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Co3-xCrxO4 spinel oxides for propane total oxidation: Essential roles of metal cations in octahedral coordination J. Catal. (IF 7.3) Pub Date : 2024-03-11 Li-Li Xu, He-Xian Li, Bi-Wen Gao, Lu-Lu Huang, Ai-Ping Jia, Yu Wang, Yun Zhao, Ji-Qing Lu
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Redox oxidative dehydrogenation of ethylbenzene over Mn–Al–O composites using active lattice oxygen at moderate temperatures J. Catal. (IF 7.3) Pub Date : 2024-03-09 Fuping Song, Juping Zhang, Dongfang Li, Tao Zhu, Xing Zhu, Hua Wang
The chemical looping oxidative dehydrogenation (CL-ODH) process divides the conventional gas–gas reaction into two gas–solid reactions to prevent direct contact between reactants and oxidants. In the ODH stage, active lattice oxygen replaces the gaseous oxygen to achieve ethylbenzene conversion and selective hydrogen combustion (SHC). In the reoxidation stage, the lattice oxygen of catalysts is replenished
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Hydrogen generation from direct Z-scheme for photocatalytic overall water splitting with the SiSe/SnSe2 and SiSe/SnSSe heterostructures J. Catal. (IF 7.3) Pub Date : 2024-03-09 Fei Wang, Chuan-Lu Yang, Xiao-Hu Li, Yu-Liang Liu, Wen-Kai Zhao
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Exploring the sustained release catalysis of CuAl2O4 spinel for highly effective CO2 conversion to CO J. Catal. (IF 7.3) Pub Date : 2024-03-09 He-Fei Kang, Ya-Jie Liu, Ye Lu, Peng Zhang, Ming-Xing Tang, Zhi-Xian Gao, Hui Ge, Wei-Bin Fan
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Metal-facilitated, sustainable nitroarene hydrogenation under ambient conditions J. Catal. (IF 7.3) Pub Date : 2024-03-08 Chongyan Ruan, Kunran Yang, Caitlin Beckett, William Martin, Eric D. Walter, Wenda Hu, Junchen Liu, Noha Zayan, Benjamin Lessin, Jacob Ken Faherty, Ryota Akutsu, Jian Zhi Hu, Fanxing Li
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Modulating metal-carrier interaction of high-loading Co-Al2O3-SiO2 catalysts for boosted N-propylcarbazole hydrogenation J. Catal. (IF 7.3) Pub Date : 2024-03-07 Li Liu, Rongyi Gao, Erxin Li, Chenggen Li, Yuan Dong, Ming Yang, Ting Zhu
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Feasible preparation of preferentially oriented (111) Pd nanocrystals supported on cyano-COFs for ultrahigh activity in C-C cross-couplings J. Catal. (IF 7.3) Pub Date : 2024-03-07 Rao Tao, Binyi Feng, Chengjiao Wang, Hongfei Zhang, Renjie Chen, Kong Liu, Jun Li, Xiujun Deng, Jiaoyang Li, Yepeng Yang
A new idea for the controllable preparation of highly dispersed palladium nanocrystals (PdNCs) was demonstrated in this work. PdNCs supported by cyano-based covalent organic frameworks (cyano-COFs) was successfully fabricated in MeOH without any other external reducing agent at room temperature. The as-prepared PdNCs exhibited excellent catalytic performance in C-C cross-couplings including Suzuki-Miyaura
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On the reactivity and selectivity trends in the tandem Diels-Alder cycloaddition and dehydrative aromatization between dimethylfuran and ethene over solid acids J. Catal. (IF 7.3) Pub Date : 2024-03-06 Shugang Sun, Cong Fu, Xin Yu, Xianfeng Yi, Anmin Zheng, Yu Gu, Hui Shi
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Design of efficient supported Pd-Co catalysts for selective hydrogenation of acetylene J. Catal. (IF 7.3) Pub Date : 2024-03-06 Daria V. Yurpalova, Tatyana N. Afonasenko, Igor P. Prosvirin, Andrey V. Bukhtiyarov, Larisa M. Kovtunova, Zakhar S. Vinokurov, Mikhail V. Trenikhin, Evgeny Yu. Gerasimov, Evgeny V. Khramov, Dmitry A. Shlyapin
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Pinwheel-like tridentate phosphines for controlling divergent regioselectivity in Pd-catalyzed alkoxycarbonylation of alkenes J. Catal. (IF 7.3) Pub Date : 2024-03-06 Tian-Hong Jing, Yi-Ying Zhuang, Xiao-Xin Zhang, Jian-Guo Qian, Xiao-Li Zhao, Yong Lu, Hai-Jing Wang, Ye Liu
Ligand-controlled divergent regioselectivity in Pd-catalyzed alkoxycarbonylation of alkenes.
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Iron-doped copper-cobalt sulfide nano-box derived from ZIF-67 as a high-efficiency heterogeneous catalyst for hydrogenation of 4-nitrophenol J. Catal. (IF 7.3) Pub Date : 2024-03-05 Huifang Lv, Yanli Gong, Zexiang Chen, Ke Yu, Zhiyu Zhou, Hualiang Wei, Yang Zhao, Mengyao Bao, Yan Wang
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Highly efficient synthesis of imine activated by noble-metal-free CuInS2/C composite catalyst from MOFs under mild conditions J. Catal. (IF 7.3) Pub Date : 2024-03-04 Peng-Fei Guo, Le-Yan Li, Hang Xu, Bin Zhao
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Porous C3N4 nanosheet supported Au single atoms as an efficient catalyst for enhanced photoreduction of CO2 to CO J. Catal. (IF 7.3) Pub Date : 2024-03-03 Shan Hu, Panzhe Qiao, Zixin Liu, Xueli Zhang, Fangyuan Zhang, Jinhua Ye, Defa Wang
Porous CN nanosheets supported Au single atoms photocatalyst (Au@CN) with AuN coordination favors CO adsorption/activation, *COOH generation, and dynamic transfer of photogenerated charge carriers, thereby significantly enhancing the CO photoreduction activity and CO selectivity.
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Theoretical exploration of CO2 photocatalytic reduction using single atom gold nanoparticles (Au0) modified SrTi0.875Hf0.125O3 J. Catal. (IF 7.3) Pub Date : 2024-03-02 Yan Cai, Changcheng Chen, Feng Chen, Songya Wang, Ziyi Zhang, Shuli Gao, Shuangna Guo, Wen Chen, Elyas Abduryim, Ying Liu, Xiaoning Guan, Gang Liu, Pengfei Lu
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Identifying a superior Ptδ+ species for the hydrogen-borrowing amination of alcohol at low temperature J. Catal. (IF 7.3) Pub Date : 2024-03-02 Shengchao Jia, Tao Tong, Xiaohui Liu, Yong Guo, Lin Dong, Zupeng Chen, Yanqin Wang
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Electrocatalytic epoxidation of cyclooctene to epoxides driven by cobalt-containing polyoxometalate J. Catal. (IF 7.3) Pub Date : 2024-03-02 Ziru Wang, Jinxiu Zhai, Yali Zhao, Wei Wang, Zhiyi Lu, Peilei He
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Improving the rigor and reproducibility of catalyst testing and evaluation in the laboratory J. Catal. (IF 7.3) Pub Date : 2024-03-02 David W. Flaherty, Aditya Bhan
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Unraveling the impact of temperature on the reaction kinetics of the electro-oxidation of methanol on Pt(1 0 0) J. Catal. (IF 7.3) Pub Date : 2024-03-01 Enrique A. Paredes-Salazar, Alfredo Calderón-Cárdenas, Enrique Herrero, Hamilton Varela
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Versatile stereoselective oxidative alkoxycarbonylation of styrenes at room-temperature J. Catal. (IF 7.3) Pub Date : 2024-03-01 Diego Olivieri, Michele Verboni, Riccardo Tarroni, Stefano Zacchini, Simone Lucarini, Nicola Della Ca', Raffaella Mancuso, Bartolo Gabriele, Carla Carfagna
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Complete electrocatalytic defluorination of perfluorooctane sulfonate in aqueous solution with nonprecious materials J. Catal. (IF 7.3) Pub Date : 2024-02-29 Ziyi Meng, Madeleine K. Wilsey, Connor P. Cox, Astrid M. Müller
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Quantity of saturated adsorbed ionomers on Pt surface in proton exchange membrane fuel cells J. Catal. (IF 7.3) Pub Date : 2024-02-29 Yi Wang, Fen Zhou, Jiayi Tao, Jinting Tan, Mu Pan
Ionomers play a pivotal role in providing a three-phase interface, proton conduction medium, catalyst binder and ink dispersant, which is an indispensable part of PEMFCs. In particular, the ionomer at the three-phase interface promotes the electrochemical reaction, but its specific adsorption on the Pt surface will poison the catalyst and hinder gas transport. Therefore, it is critical to quantify
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Crystal-facet-dependent, electron sink effect for the enhanced selective oxidation of polyols at the secondary hydroxyl position J. Catal. (IF 7.3) Pub Date : 2024-02-29 Hao Yan, Mingyue Zhao, Yueqiang Cao, Xin Zhou, Yibin Liu, Xiaobo Chen, Xiang Feng, Xuezhi Duan, Francisco Zaera, Xinggui Zhou, Chaohe Yang
Three morphologies of ZnO [spherical (S), rod (R) and disk (D)] were synthesized and tested as supports for Au nanoparticles for the selective oxidation of glycerol, 1,2-propanediol, 1,2-butanediol, and isopropanol at their secondary hydroxyl group to produce the corresponding ketones. The Au-ZnO(001) interface exhibits a strong electron sink effect and abundant oxygen vacancies, greatly promoting
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Influence of CO adsorption on the structure of electric double layer on Cu surface J. Catal. (IF 7.3) Pub Date : 2024-02-28 Jiajie Hou, Qi Lu
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Mechanochemistry-based liquid-assisted synthesis of hydrophobic Zr-Beta with high metal loading for Meerwein-Ponndorf-Verley reduction J. Catal. (IF 7.3) Pub Date : 2024-02-27 Hongwei Zhang, Stephan Jaenicke, Kazu Okumura, Hui-Ru Tan, Gaik-Khuan Chuah
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Potassium and chlorine co-tuned graphitic carbon nitride for organic pollutants photodegradation: Revealing the effects of cyano groups on O2 evolution J. Catal. (IF 7.3) Pub Date : 2024-02-25 Chen Yang, Jian Yang, Yujie Fang, Huan Li, Xu Duan, Runxue Liu, Lang Liu, Chunlian Ding, Weizao Liu, Qingcai Liu
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Enhanced regioselectivity in propylene hydroformylation using Xantphos-modified single-atom Rh/CeO2 catalyst J. Catal. (IF 7.3) Pub Date : 2024-02-24 Ying Zheng, Qi Yang, Sikai Wang, Shinya Furukawa, Pengfei Wang, Maoshuai Li, Ning Yan, Xinbin Ma
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Dynamic interactions between adsorbates and catalyst surfaces over long-term OER stability testing in acidic media J. Catal. (IF 7.3) Pub Date : 2024-02-24 Ruihan Li, Bingzhang Lu, Jane Edgington, Linsey C. Seitz
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Hydrogenation of CO2 to CH3OH catalyzed by a ruthenium-triphos complex: Theoretical free energy profile and microkinetic modeling J. Catal. (IF 7.3) Pub Date : 2024-02-24 Ellen V. Dalessandro, Josefredo R. Pliego Jr
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Benzothiadiazole-functionalized Zr-MOF nanosheets enable visible-light mediated photocatalytic oxidation of sulfides in water J. Catal. (IF 7.3) Pub Date : 2024-02-24 Yu-Liang Chong, Dong-Dong Zhao, Mi Yan, Xing-Yu Zhou, Jun-Jie Zhang, Bing Wang, Zhuo Chen, Jin-Liang Zhuang
Water stable Zr-BTDB ultrathin nanosheets incorporated with benzothiadiazole moieties enable efficient aerobic oxidation of a wide range of sulfides to sulfoxides under visible light irradiation in water at room temperature.
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Developing and understanding Leaching-Resistant cobalt nanoparticles via N/P incorporation for liquid phase hydroformylation J. Catal. (IF 7.3) Pub Date : 2024-02-24 Carmen Galdeano-Ruano, Silvia Gutiérrez-Tarriño, Christian W. Lopes, Jaime Mazarío, Lidia E. Chinchilla, Giovanni Agostini, Jose J. Calvino, Juan P. Holgado, Enrique Rodríguez-Castellón, Alberto Roldan, Pascual Oña-Burgos
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Surface ZnOx on zirconia is highly active for high temperature methanol synthesis J. Catal. (IF 7.3) Pub Date : 2024-02-23 M.T. Nikolajsen, J.-C. Grivel, A. Gaur, L.P. Hansen, L. Baumgarten, N.C. Schjødt, U.V. Mentzel, J.-D. Grunwaldt, J. Sehested, J.M. Christensen, M. Høj
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Screening support effect of Pt/MOx for selective hydrogenation of cinnamaldehyde J. Catal. (IF 7.3) Pub Date : 2024-02-23 Liwei Wang, Yanfu Ma, Haitao Li, Wenhao Luo, Jian Liu
Scheme of CAL hydrogenation on Pt/MO. Metallic Pt activates and dissociates H. Next, active H species dissociated from H spill though Pt to oxides supports. At the same time, substrates adsorb on the support with preferential behavior to be hydrogenated with spilled active species to accomplish the progress of cinnamaldehyde hydrogenation.
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CH3 radical-mediated direct methane to methanol conversion over CuO supported on rutile oxides J. Catal. (IF 7.3) Pub Date : 2024-02-21 Huixian Liu, Yuyao Qin, Liwen Li, Hua Wang, Xinli Zhu, Qingfeng Ge
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Mechanistic study of alkene hydrogenation catalyzed by cationic Ni(II)-hydride PNHP complexes – Ni(II/IV) vs. Ni(II) cycle J. Catal. (IF 7.3) Pub Date : 2024-02-19 Zhihong Wei, Yunjuan Ren, Xinxin Tian, Chaoren Shen, Haijun Jiao
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Palladium-catalyzed directly carbonylative synthesis of fluoro-substituted malonates from (fluoro)bromoacetates J. Catal. (IF 7.3) Pub Date : 2024-02-18 Zhi-Peng Bao, Xiao-Feng Wu
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Structure sensitivity in adsorbate-induced adatom formation on FCC transition-metal surfaces J. Catal. (IF 7.3) Pub Date : 2024-02-18 Lang Xu, Manos Mavrikakis
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ZIF-8 derived ZnO@NC supported Ru nanoparticles for efficient low-temperature hydrogenation of levulinic acid to γ-valerolactone J. Catal. (IF 7.3) Pub Date : 2024-02-17 Xiaoqing Gao, Shanhui Zhu, Mei Dong, Hongyan Zheng, Yanfeng Xue, Xiaojing Cui, Yulan Niu, Weibin Fan
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Bifunctional metal–acid sites on nickel boride catalysts: Phenol hydrodeoxygenation and water-promoted C = C hydrogenation J. Catal. (IF 7.3) Pub Date : 2024-02-17 Gengnan Li, Thomas Salas, Shoutian Sun, Bin Wang, Mallikharjuna Rao Komarneni, Daniel E. Resasco
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Fluorine-induced enhancement of the photocatalytic activity in Ti-based Metal-Organic Frameworks J. Catal. (IF 7.3) Pub Date : 2024-02-15 Nikita Kolobov, Luis Garzon-Tovar, Tuiana Shoinkhorova, Genrikh Shterk, Sang-Ho Chung, Alejandra Rendón-Patiño, Abdulrahman Alfaraidi, Javier Ruiz-Martínez, Christopher H. Hendon, Jorge Gascon
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Recent progress in the development of electrode materials for electrochemical carboxylation with CO2 J. Catal. (IF 7.3) Pub Date : 2024-02-15 Thu N. Ton, Rachel J. Baker, Karthish Manthiram
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Enhancing photocatalytic performance of atom transfer radical addition (ATRA) reactions in water using immobilized 10-Phenylphenothiazine catalysts on mesoporous silica supports J. Catal. (IF 7.3) Pub Date : 2024-02-15 Montaña J. García, Thomas A. Comerford, Carmen Montoro, Eli Zysman-Colman, José Alemán, Silvia Cabrera
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Understanding oxygen reduction reaction activity of Pt-based nanoparticles from Pt atomic layers to Pt single atom alloy J. Catal. (IF 7.3) Pub Date : 2024-02-13 Xiaoyu Huang, Haoxiang Xu, Jiqin Zhu, Daojian Cheng
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Novel porous organic polymer supported chloramphenicol base derivatives: A highly enantioselective, recyclable heterogeneous organocatalyst for asymmetric desymmetrization reaction J. Catal. (IF 7.3) Pub Date : 2024-02-13 Yi-Ren Zhu, Jie Zhong, Fei Xiong
We developed a series of porous organic polymer (POP) supported chloramphenicol base (ANP) derived organocatalysts with different polymeric condition or molecule structure and applied it to the asymmetric alcoholysis of cyclic -anhydrides. The optimal POP catalyst shows great enantioselectivity and good recyclability in asymmetric organocatalysis, which are the best performance in the research of ANP
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Recommendations to standardize reporting, execution, and interpretation of X-ray Absorption Spectroscopy measurements J. Catal. (IF 7.3) Pub Date : 2024-02-12 Randall J. Meyer, Simon R. Bare, Griffin A. Canning, Jingguang G. Chen, Pamela M. Chu, Adam S. Hock, Adam S. Hoffman, Ayman M. Karim, Shelly D. Kelly, Yu Lei, Eli Stavitski, Cody J. Wrasman
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Electrocatalytic oxygen reduction on metalloporphyrins. Second coordination sphere substituents on the ligand: Electronic and steric effects through pocket and extended structures and their effect on the electrocatalytic activity J. Catal. (IF 7.3) Pub Date : 2024-02-10 Carlos P. Silva, Carolina P. Candia, Mauricio Paredes, Elizabeth Imbarack, Fabian Martínez-Gómez, Camila F. Olguín, Geraldine Jara, José H. Zagal, Jorge Pavez, Nicolás Agurto
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Critical removal of surface carbonates on γ-Al2O3 to enhance nucleation of Pt atomic layer deposition J. Catal. (IF 7.3) Pub Date : 2024-02-10 Huimin Yang, Xinchun Yang, Fanchun Meng, Shufang Zhang, Shichao Zhao, Bin Zhang, Yong Qin
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Theoretical investigation of the paring mechanism of the MTO process in different zeolites J. Catal. (IF 7.3) Pub Date : 2024-02-10 Annika E. Enss, Philipp N. Plessow, Felix Studt
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Large-scale comparison of Fe and Ru polyolefin C–H activation catalysts J. Catal. (IF 7.3) Pub Date : 2024-02-09 Husain Adamji, Ilia Kevlishvili, Aditya Nandy, Yuriy Román-Leshkov, Heather J. Kulik
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Photocatalytic oxidation mechanism of isoprene over titanium oxide by UV–Vis lights J. Catal. (IF 7.3) Pub Date : 2024-02-09 Boying Song, Zongcheng Wang, Wei Ma, Wenshuo Zhou, Qiong Tang, Xiaolei Bao, Kuo Liu, Yongchun Liu
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Unraveling the role of basic sites in the hydrogenation of CO2 to formic acid over Ni-based catalysts J. Catal. (IF 7.3) Pub Date : 2024-02-08 Yixuan Wang, Hongyan Ban, Yugao Wang, Ruwei Yao, Shimin Zhao, Jiangliang Hu, Congming Li
The weak basic site is the primary puller of the reaction process, while medium basic sites guarantee fundamental catalytic activity. The weak and medium basic sites synergistically catalyze the hydrogenation of CO to formic acid.
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Mechanistic control of surface chlorine within propylene epoxidation J. Catal. (IF 7.3) Pub Date : 2024-02-08 Joseph Esposito, Aditya Bhan
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